Industrial use of arsenic compounds, in view of the risk attaching to
them, should be reduced as much as possible. This has sometimes been
achieved by technical improvement in processes of manufacture. Thus in
the colour industry, where formerly colours containing arsenic played
an important rôle, coal-tar colours have taken their place, and use
of arsenic even in these (as in the manufacture of fuchsin) has been
replaced by nitrobenzene.
As the danger from arseniuretted hydrogen gas is especially great in
processes in which acid acts on metal and either one or both of them
contain arsenic, the materials, should be as free from arsenic as
possible, in the production, for example, of hydrogen for soldering, in
extracting metals by means of acids, in galvanic elements, in accumulator
works, in the storage and transport of acids in metal vessels, and in
galvanising.
In any case the workers in these industries should be warned of the
danger and instructed in case of emergencies. For soldering exclusive use
of hydrogen produced electrolytically and procurable in steel cylinders
is advisable.
Extraction and Use of Gold and Silver
In the extraction of gold and silver by amalgamation and subsequent
volatilisation of mercury there is risk of mercurial poisoning. The
preventive measures necessary are similar to those for poisoning in the
recovery of mercury (see p. 327).
_Argyria_ in pearl bead blowers can be avoided by using pumps to blow the
silver solution into the beads instead of the mouth.
In electroplating the possibility of poisonous fumes arising from the
baths must be guarded against because hydrocyanic (prussic) acid, though
only in minute quantities, may be evolved; care must be taken that the
workrooms are well ventilated or the baths hooded. Careful personal
hygiene is essential, for the prevention of skin diseases from which
workers in electroplating often suffer.
VII
_PREVENTIVE MEASURES IN OTHER TRADES_
Ceramic Industry
In the glass industry use of lead, chrome, and arsenic compounds should
be restricted as much as possible or allowed only under suitable
precautions (exhaust ventilation, personal hygiene, &c.).
_Etching on glass_ by means of hydrofluoric causes almost inevitably
injury to the workers. Rendering the surface of glass opaque should
preferably be done by sand blast. When a bath of hydrofluoric acid for
etching on glass is used the fumes require to be drawn away by hoods over
the baths and the work-rooms well ventilated.
Further precautionary measures are called for in view of industrial
poisoning by furnace gases in various ceramic industries, as, for
example, cement works, glass works, and tile works.
The following suggestions are made in the technical introduction to the
Germany Factory Act for prevention of poisoning from carbonic oxide,
carbon dioxide, and sulphur dioxide:
(1) Even the fixing of benches which might be used for sleeping on near
the furnaces should be strictly forbidden;
Public-domain text, read in full here on John Shaqi.
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