Manganese is also used in the production of colours: the natural and
artificial umbers contain it; in glass works it is used to decolourise
glass, and also in the production of coloured glass and glazes; in the
manufacture of stove tiles, and in the production of driers for the
varnish and oil industry. Manganese and compounds of manganese are
dangerous when absorbed into the system as dust.
Already in 1837 nervous disorders had been described in workmen who
ground manganese dioxide.[1] The malady was forgotten, until Jaksch[2]
in Prague in 1901 demonstrated several such cases in persons employed
in a large chemical factory in Bohemia, from the drying of Weldon mud.
In the same year three similar cases were also described in Hamburg.[3]
In 1902 Jaksch observed a fresh case of poisoning, and in the factory
in question described a condition of manganophobia among the workers,
obviously hysterical, in which symptoms of real manganese poisoning were
simulated. In all some twenty cases are known. Jaksch is of opinion that
it is manganese dust rich in manganese protoxide that is alone dangerous,
since, if the mud has been previously treated with hydrochloric acid, by
which the lower oxides are removed, no illness can be found. The most
dangerous compounds are MnO and Mn₃O₄.
PETROLEUM
OCCURRENCE AND USES.—Crude petroleum flows spontaneously from wells in
consequence of high internal pressure of gas or is pumped up. In America
and Russia also it is conveyed hundreds of miles in conduits to the ports
to be led into tank steamers.
The crude oil is a dark-coloured liquid which, in the case of
Pennsylvanian mineral oil, consists mainly of a mixture of hydrocarbons
of the paraffin series, or, in Baku oil, of those of the naphtha series.
There are in addition sulphur compounds, olefines, pyridin, &c. The
crude oil is unsuitable for illuminating purposes and is subjected to a
distillation process. It is split up into three fractions by a single
distillation, namely, (_a_) benzines (boiling-point 150° C.), (_b_)
lighting oil (boiling-point 150°-300° C.); at a temperature of 300° C.
the distillation is stopped so that (_c_) the residuum boiling above 300°
C. remains. Distillation is effected (in America) in large stills, in
which periodically benzine and lighting oil up to 300° C. is distilled
and the residuum run off. In Baku continuously working batteries of
so-called cylindrical boilers are used, into which the crude oil
streams. In the first set of boilers, the temperature in which rises to
150° C., the benzine is distilled off, and in the succeeding ones, heated
to 300° C., the illuminating petroleum oils (kerosine), the residuum
flowing continually away.
The _mineral oil residues_ are used as fuel. Heating by this means,
tried first only in Russia, is spreading, especially for the heating of
boilers, in which case the liquid fuel is blown in generally as a spray.
The combustion if rightly planned is economical and almost smokeless.
Public-domain text, read in full here on John Shaqi.
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