The American oil residuum, rich in paraffin, is distilled, the distillate
is cooled and separated by pressure into solid paraffin and liquid oil.
The latter and the Russian mineral oil residues which are free from
paraffin are widely used as lubricants. In the production of lubricants
the residues are distilled at low temperature (in vacuo or by aid of
superheated steam) and separated into various qualities by fractional
cooling, are then purified with sulphuric acid, and finally washed with
caustic soda solution.
In the preparation of vaseline the residum is not distilled, but purified
only with fuming sulphuric acid and decolourised with animal charcoal.
The _illuminating oil_ is next subjected to a purifying process
(refining); it is first treated with sulphuric acid and well agitated
by means of compressed air. The acid laden with the impurities is drawn
off below, and the oil freed from acid by washing first with caustic
soda and subsequently with water. It is then bleached in the sun. For
specially fine and high flash point petroleum the oil undergoes a further
distillation and purification with acid.
The fractions of crude petroleum with low boiling-point (under 150° C.)
are known commercially as raw _benzine_ or _petrol naphtha_. It is used
for cleaning, in extraction of fats and oils, and for benzine motors.
Frequently raw benzine is subjected to a purifying process and to
fractional distillation. Purification is carried out by means of
sulphuric acid and soda liquor and subsequent separation into three
fractions and a residue which remains in the retort—(_a_) _petroleum
ether_ (called gasoline, canadol, and rhigoline), which comes over
between 40° and 70° C., and serves for carburetting water gas and other
similar gases, as a solvent for resin, oil, rubber, &c.; (_b_) _purified
benzine_ (70°-120° C.) is used as motor spirit and in chemical cleaning;
(_c_) _ligroine_ (120°-135° C.), used for illuminating purposes; and
(_d_) the _residual oil_ (above 135° C.) serves for cleaning machinery
and, especially, as a solvent for lubricating oil, and instead of
turpentine in the production of lacquers, varnishes, and oil colours.
In _chemical cleaning_ works benzine is used in closed-in washing
apparatus, after which the clothes are centrifugalised and dried. In
view of the risk of fire in these manipulations, originating mainly from
frictional electricity, various substances are recommended to be added
to the benzine, of which the best known is that recommended by Richter,
consisting of a watery solution of oleate of sodium or magnesium.
Public-domain text, read in full here on John Shaqi.
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