A worker in a paraffin factory had entered an open benzine still to
scrape the walls free of crusts containing benzine. He was found
unconscious and died some hours later. It appeared that he had been in
the still several hours, having probably been overcome to such an extent
by the fumes as to be unable to effect his escape.
Attempt to wipe up benzine spilt in the storage cellar of a large
chemical cleaning works resulted in poisoning.
A night worker in a bone extracting works having turned on the steam,
instead of watching the process fell asleep on a bench. In consequence
the apparatus became so hot that the solder of a stop valve melted,
allowing fumes to escape. The man was found dead in the morning. In a
carpet cleaning establishment three workers lost consciousness and were
found senseless on the floor. They recovered on inhalation of oxygen.
One further case reported from the instances of benzine poisoning
collected recently[9] is worth quoting. A worker in a chemical factory
was put to clean a still capable of distilling 2500 litres of benzine.
It contained remains of a previous filling. As soon as he had entered
the narrow opening he became affected and fell into the benzine; he
was carried unconscious to the hospital, his symptoms being vomiting,
spastic contraction of the extremities, cyanosis, weak pulse, and loss of
reflexes, which disappeared an hour and a half later.
The occurrence of skin affections in the naphtha industry has been noted
by several observers, especially among those employed on the unpurified
mineral oils. Eruptions on the skin from pressing out the paraffin and
papillomata (warty growths) in workers cleaning out the stills are
referred to by many writers,[10] Ogston in particular.
Recent literature refers to the occurrence of petroleum eczema in a
firebrick and cement factory. The workers affected had to remove the
bricks from moulds on to which petroleum oil dropped. An eczematous
condition was produced on the inner surface of the hands, necessitating
abstention from work. The pustular eczema in those employed only a short
time in pressing paraffin in the refineries of naphtha factories is
referred to as a frequent occurrence. Practically all the workers in
three refineries in the district of Czernowitz were affected. The view
that it is due to insufficient care in washing is supported by the report
of the factory inspector in Rouen, that with greater attention in this
matter on the part of the workers marked diminution in its occurrence
followed.
SULPHUR
RECOVERY AND USE.—Sulphur, which is found principally in Sicily (also in
Spain, America, and Japan), is obtained by melting. In Sicily this is
carried out in primitive fashion by piling the rock in heaps, covering
them with turf, and setting fire to them. About a third of the sulphur
burns and escapes as sulphur dioxide, while the remainder is melted and
collects in a hole in the ground.
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