The crude sulphur thus wastefully produced is purified by distillation in
cast-iron retorts directly fired. It comes on the market as stick or roll
sulphur or as flowers of sulphur.
Further sources for recovery of sulphur are the Leblanc soda residues
(see Soda Production), from which the sulphur is recovered by the
Chance-Claus process, and the gas purifying material (containing up to 40
per cent.), from which the sulphur can be recovered by carbon bisulphide
(see Illuminating Gas Industry).
The health conditions of the Sicilian sulphur workers are very
unsatisfactory, due, however, less to the injurious effect of the
escaping gases (noxious alike to the surrounding vegetation) than to the
wretched social conditions, over exertion, and under feeding of these
workers.
Of importance is the risk to health from sulphuretted hydrogen gas,
from sulphur dioxide in the recovery of sulphur from the soda residues,
and from carbon bisulphide in the extraction of sulphur from the gas
purifying material.
SULPHURETTED HYDROGEN GAS
Sulphuretted hydrogen gas is used in the chemical industry especially
for the precipitation of copper in the nickel and cobalt industry, in
de-arsenicating acid (see Hydrochloric and Sulphuric Acids), to reduce
chrome salts in the leather industry, &c. In addition it arises as a
product of decomposition in various industries, such as the Leblanc soda
process, in the preparation of chloride of antimony, in the decomposition
of barium sulphide (by exposure to moist air), in the treatment of gas
liquors, and in the preparation of carbon bisulphide: it is present
in blast furnace gas, is generated in mines (especially in deep seams
containing pyrites), arises in tar distillation, from use of gas lime
in tanning, and in the preparation and use of sodium sulphide: large
quantities of the gas are generated in the putrefactive processes
connected with organic sulphur-containing matter such as glue making,
bone stores, storage of green hides, in the decomposition of waste water
in sugar manufacture and brewing, in the retting of flax, and especially
in sewers and middens.
Both _acute_ and _chronic_ poisoning are described.
Public-domain text, read in full here on John Shaqi.
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