USE OF CYANIDES.—Potassium cyanide is principally used in the recovery
of gold, in gold and silver electroplating, in photography, for
soldering (it reduces oxides and makes metallic surfaces clean), for
the production of other cyanogen compounds, for the removal of silver
nitrate stains, &c. Hydrocyanic acid gas is given off in electroplating,
photography, in smelting fumes, in tanning (removing hair by gas lime),
&c.
EFFECTS ON HEALTH.—Industrial cyanogen poisoning is rare. Weyl[1] states
that he could find no case in any of the German factory inspectors’
reports for the twenty years prior to 1897, nor in some twenty-five
volumes of foreign factory inspectors’ reports. I have found practically
the same in my search through the modern literature.
Of the very few references to the subject I quote the most important.
A case of (presumably) chronic hydrocyanic acid poisoning is described in
a worker engaged for thirteen years in silver electroplating of copper
plates.[2] The plates were dipped in a silver cyanide solution and then
brushed. After two years he began to show signs of vomiting, nausea,
palpitation, and fatigue, which progressed and led to his death.
A case of sudden death is described[3] occurring to a worker in a sodium
cyanide factory who inhaled air mixed with hydrocyanic acid gas from a
leaky pipe situated in a cellar. The factory made sodium cyanide and
ammonium sulphate from the residue after removal of the sugar from
molasses. This is the only definite case of acute cyanogen poisoning in a
factory known to me. I believe that under modern conditions, in which the
whole process is carried on under negative pressure, chance of escape of
cyanogen gases is practically excluded.
It should be mentioned that hydrocyanic acid vapour is given off in the
burning of celluloid. In this way eight persons were killed at a fire in
a celluloid factory.[4]
Skin affections are said to be caused by contact with fluids containing
cyanogen compounds, especially in electroplating. It is stated that
workers coming into contact with solutions containing cyanides may
absorb amounts sufficient to cause symptoms, especially if the skin
has abrasions. Such cases are described.[5] In electroplating, further,
in consequence of the strong soda solutions used, deep ulceration and
fissures of the skin of the hand can be caused.
COAL TAR AND TAR PRODUCTS
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