The roast and reaction process is carried out in specially constructed
reverberatory furnaces; small furnaces with small amounts of ore and at
as low a temperature as possible are the rule in the Kärntner process.
In the English process large amounts of ore are melted in large furnaces
at high temperatures so as to oxidise the material. The so-called
Tarnowitz process combines these two—large amounts of ore are roasted
in large furnaces at a moderate temperature. In the roast and reduction
process it depends on the nature of the ore whether the roasting is done
in reverberatory or blast furnaces. Generally the ore is in the form
of powder—less often in pieces. Pyritic ore (ore with much sulphur) is
almost always roasted in blast furnaces, and the sulphur dioxide evolved
can be used in the manufacture of sulphuric acid. Open-hearth furnaces
are rarely used now. Reverberatory furnaces are employed most frequently.
The lead thus obtained contains several other metals, especially silver,
copper, arsenic, antimony, iron, zinc, bismuth, and tin. Lead containing
silver (work-lead) is next _de-silverised_, after which follows refining
to get rid of the other impurities. For de-silverising work-lead rich
in silver (containing about 10 per cent.) _cupellation_ is practised,
in which the silver lead is melted and oxidised so that the lead is
converted into _litharge_, metallic silver remaining behind. In a
cupellation furnace the flame strikes on the top of the lead bath, and
at the same time air under slight pressure is driven in; the litharge
which forms is removed through suitable openings. The litharge that is
first formed contains silver and is treated again; the remainder is ready
for market. After the litharge has run off silver appears, containing
still 5-10 per cent. of lead, and it is again submitted to an analogous
refining process. Work-lead which does not contain enough silver to be
cupelled at once is generally treated first by either the Pattinson or
the Parkes’ process.
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