Inventors at Work, with Chapters on DiscoveryIles, George
History
Inventors at Work, with Chapters on Discovery
Iles, George
Inventions -- History; Inventors
From Indian handicrafts, developed by aboriginal skill, patience and
good taste to remarkable triumphs, let us turn to an achievement of a
modern chemist who, calling electricity to his aid, bestowed a new metal
upon industry, making possible new economies in a wide sisterhood of
arts. Aluminium was discovered in 1828 by Wohler, a German chemist, who
noted its lightness, toughness, and ductility. At the Centennial
Exhibition at Philadelphia, in 1876, a surveyor’s transit built of
aluminium was shown, but the metal at that time was six-fold the price
of silver, so that the instrument for some years remained uncopied. Of
course, engineers and mechanics were much interested in a metal only
about one-third as heavy as brass or copper, of white lustre, and with
as much as five-eighths the electrical conductivity of copper. All that
hindered the extensive use of the metal was its high cost. If that cost
could be lowered, at once copper, and even silver, would face a rival.
After many unsuccessful because expensive processes for obtaining the
metal had been devised, a method was found at once simple and
inexpensive.
This method of separating aluminium from its compounds was devised by
Charles M. Hall, while an undergraduate student at Oberlin College,
Ohio. His success turned on his knowledge of the properties of related
metallic compounds. He recognized the probable value of aluminium in
the arts, could it be produced in large quantity at low cost. He
believed that electrolysis would prove the most convenient, thorough and
inexpensive method; but there was at that time no process known by which
it could be applied to this element. His problem was to find a form of
electrolyte rich in aluminium which should be comparatively easy to
separate into its elements, and to discover a substance for the solvent
which should prove a satisfactory bath. This latter substance must,
furthermore, be a good conductor of electricity, must readily dissolve
the proposed electrolyte, and must have a higher resistance to
electrolytic disruption than the electrolyte. To discover the needed
substances for electrolyte and solvent involved the examination of all
available compounds of aluminium, the study of the various possible
solvents for the compound selected, and the determination of electric
conductivities. By virtue of rare familiarity with the chemistry and
physics of the subject, with the properties of every substance
concerned, the search was, after a time, rewarded with complete success.
It was found that bauxite--the oxide of aluminium, alumina, in fact--is
dissolved by molten cryolite, the double silicate of aluminium and
sodium, and that the latter, while dissolving the bauxite freely and
serving as an ideal solvent, also itself breaks up under the action of
the electric current at a much higher voltage than alumina. So far as
known, these are the only substances in nature which stand to each other
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