James Clerk Maxwell and Modern PhysicsGlazebrook, Richard
History
James Clerk Maxwell and Modern Physics
Glazebrook, Richard
Maxwell, James Clerk, 1831-1879; Physics -- History
The simplest theory we could formulate would be that the molecules
behaved like elastic spheres, and that the action between any two was
a collision following the laws which we know apply to the collision of
elastic bodies. If the average distance between two molecules be great
compared with their dimensions, the time during which any molecule
is in collision will be small compared with the interval between the
collisions, and this is in accordance with the fundamental assumption
just mentioned. It is not, however, necessary to suppose an encounter
between two molecules to be a collision. One molecule may act on
another with a force, which depends on the distance between them, of
such a character that the force is insensible except when the molecules
are extremely close together.
It is not difficult to see how the pressure exerted by a gas on the
sides of a vessel which contains it may be accounted for on this
assumption. Each molecule as it strikes the side has its momentum
reversed--the molecules are here assumed to be perfectly elastic.
Thus each molecule of the gas is continually gaining momentum from
the sides of the vessel, while it gives up to the vessel the momentum
which it possessed before the impact. The rate at which this change of
momentum proceeds across a given area measures the force exerted on
that area; the pressure of the gas is the rate of change of momentum
per unit of area of the surface.
Again, it can be shown that this pressure is proportional to the
product of the mass of each molecule, the number of molecules in a unit
of volume, and the square of the velocity of the molecules.
Let us consider in the first instance the case of a jet of sand or
water of unit cross section which is playing against a surface. Suppose
for the present that all the molecules which strike the surface have
the same velocity.
Then the number of molecules which strike the surface per second, will
be proportional to this velocity. If the particles are moving quickly
they can reach the surface in one second from a greater distance than
is possible if they be moving slowly. Again, the number reaching the
surface will be proportional to the number of molecules per unit of
volume. Hence, if we call _v_ the velocity of each particle, and N
the number of particles per unit of volume, the number which strike
the surface in one second will be N _v_; if _m_ be the mass of each
molecule, the mass which strikes the surface per second is N _m_ _v_;
the velocity of each particle of this mass is _v_, therefore the
momentum destroyed per second by the impact is N _m_ _v_ × _v_, or N
_m_ _v_², and this measures the pressure.
Hence in this case if _p_ be the pressure
_p_ = N _m_ _v_².
Public-domain text, read in full here on John Shaqi.
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