James Clerk Maxwell and Modern PhysicsGlazebrook, Richard
History
James Clerk Maxwell and Modern Physics
Glazebrook, Richard
Maxwell, James Clerk, 1831-1879; Physics -- History
Consider two streams of gas, moving in opposite directions one over
the other; it is found that in each case the layers of gas near the
separating surface move more slowly than those in the interior of
the streams; there is apparently a frictional force between the two
streams along this surface, tending to reduce their relative velocity.
Maxwell’s explanation of this is that at the common surface particles
from the one stream enter the other, and carry with them their own
momentum; thus near this surface the momentum of each stream is
reduced, just as the momentum of the trains is reduced by the people
jumping across. Internal friction or viscosity is due to the diffusion
of momentum across this common surface. The effect does not penetrate
far into the gas, for the particles soon acquire the velocity of the
stream to which they have come.
Now, the rate at which the momentum is diffused will measure the
frictional force, and will depend on the mean free path of the
particles. If this is considerable, so that on the average a particle
can penetrate a considerable distance into the second gas before a
collision takes place and its motion is changed, the viscosity will be
considerable; if, on the other hand, the mean free path is small, the
reverse will be true. Thus it is possible to obtain a relation between
the mean free path and the coefficient of viscosity, and from this, if
the coefficient of viscosity be known, a value for the mean free path
can be found.
Maxwell, in the paper under discussion, was the first to do this,
and, using a value found by Professor Stokes for the coefficient of
viscosity, obtained as the length of the mean free path of molecules
of air 1/447000 of an inch, while the number of collisions per second
experienced by each molecule is found to be about 8,077,200,000.
Moreover, it appeared from his theory that the coefficient of viscosity
should be independent of the number of molecules of gas present, so
that it is not altered by varying the density. This result Maxwell
characterises as startling, and he instituted an elaborate series of
experiments a few years later with a view of testing it. The reason
for this result will appear if we remember that, when the density is
decreased, the mean free path is increased; relatively, then, to the
total number of molecules present, the number which cross the surface
in a given time is increased. And it appears from Maxwell’s result that
this relative increase is such that the total number crossing remains
unchanged. Hence the momentum conveyed across each unit area per second
remains the same, in spite of the decrease in density.
Another consequence of the same investigation is that the coefficient
of viscosity is proportional to the mean velocity of the molecules.
Since the absolute temperature is proportional to the square of the
velocity, it follows that the coefficient of viscosity is proportional
to the square root of the absolute temperature.
Public-domain text, read in full here on John Shaqi.
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