Chemists -- England -- Biography; Priestley, Joseph, 1733-1804
“Accordingly I procured some volatile spirit of sal ammoniac, and
having put it into a thin phial, and heated it with the flame of a
candle, I presently found that a great quantity of vapour was
discharged from it; and being received in a vessel of quicksilver,
standing in a basin of quicksilver, it continued in the form of a
transparent and permanent air, not at all condensed by cold; so that I
had the same opportunity of making experiments upon it as I had before
on the acid air, being in the same favourable circumstances....
Wanting, however, to procure this air in greater quantities, and this
method being rather expensive, it occurred to me that alkaline air
might probably be procured, with the most ease and convenience, from
the original materials, mixed in the same proportions that chemists
had found by experience to answer the best for the production of the
volatile spirit of sal ammoniac. Accordingly I mixed one-fourth of
pounded sal ammoniac with three-fourths of slaked lime; and filling a
phial with the mixture, I presently found it completely answered my
purpose. The heat of a candle expelled from this mixture a prodigious
quantity of alkaline air; and the same materials ... would serve me a
considerable time without changing....”
He next studied the properties of the alkaline air. He found, of course,
it was readily soluble in water.
“Having satisfied myself with respect to the relation that alkaline
air bears to water, I was impatient to find what would be the
consequence of mixing this new air with the other kinds with which I
was acquainted before, and especially with _acid_ air; having a notion
that these two airs, being of opposite natures, might compose a
_neutral air_, and perhaps the very same thing with common air. But
the moment that these two kinds of air came into contact a beautiful
white cloud was formed, and presently filled the whole vessel in which
they were contained.... When the cloud was subsided there appeared to
be formed a solid _white salt_, which was found to be the common _sal
ammoniac_, or the marine acid united to the volatile alkali....
“_Fixed air_ admitted to alkaline air formed oblong and slender
crystals.... These crystals must be the same thing with the volatile
alkalis which chemists get in a solid form by the distillation of sal
ammoniac with fixed alkaline salts....
“Alkaline air, I was surprised to find, is slightly inflammable....
“That alkaline air is lighter than acid air is evident from the
appearances that attend the mixture, which are indeed very beautiful.
When acid air is introduced into a vessel containing alkaline air, the
white cloud which they form appears at the bottom only and ascends
gradually. But when the alkaline air is put to the acid the whole
becomes immediately cloudy quite to the top of the vessel.”
Public-domain text, read in full here on John Shaqi.
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