Chemists -- England -- Biography; Priestley, Joseph, 1733-1804
“might assist in sustaining subterraneous fires.... The solution of
the phenomena of subterraneous fires would certainly be much easier on
the supposition of their supplying their own _pabulum_, by means of
dephlogisticated air contained in substances exposed to their heat. I
therefore desired Mr Landriani, who being in Italy had a good
opportunity of making inquiries on the subject, to inform me whether
any of those substances, and particularly _manganese_ be found in
their volcanoes; and his answer makes it rather probable that those
fires are, in part, sustained by this means.”
The ease with which nitre parts with its oxygen on heating furnished
Priestley with the true explanation of its so-called “detonation,”
“concerning which,” he says, “the most improbable conjectures have been
advanced by the most eminent philosophers and chemists.” After a
reference to the hypothesis of Macquer, who assumes that what he calls
“a _nitrous sulphur_” is produced, Priestley points out that
“the doctrine of dephlogisticated air supplies the easiest solution
imaginable of this very difficult phenomenon. Let any person but
attend to the phenomena of the detonation of charcoal in nitre, and
that of dipping a piece of hot charcoal into a jar of dephlogisticated
air, and I think it will be impossible for him not to conclude that
the appearances are the very same and must have the same cause.”
Of all the quantitative exercises performed by Priestley, by far the
most numerous depended upon his application of nitric oxide to measure
the “goodness” of air.
“When,” he says, “I first discovered the property of nitrous air as a
test of the wholesomeness of common air, I flattered myself that it
might be of considerable practical use, and particularly that the air
of distant places and countries might be brought and examined together
with great ease and satisfaction; but I own that hitherto I have
rather been disappointed in my expectations from it.... I gave several
of my friends the trouble to send me air from distant places,
especially from manufacturing towns, and the worst they could find to
be actually breathed by the manufacturers, such as is known to be
exceedingly offensive to those who visit them; but when I examined
those specimens of air in Wiltshire, the difference between them and
the very best air in this county, which is esteemed to be very good,
as also the difference between them and specimens of the best air in
the counties in which these manufacturing towns are situated, was very
trifling.... I have frequently taken the open air in the most exposed
places in this country at _different times of the year_, and in
different states of the _weather_, etc., but never found the
difference so great as the inaccuracy arising from the method of
making the trial might easily amount to or exceed.”
Public-domain text, read in full here on John Shaqi.
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