Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving riskLegge, Thomas Morison, Sir
Science
Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving risk
Legge, Thomas Morison, Sir
Lead poisoning
the approximate quantity inhaled per worker daily. We have summarized
some of his conclusions in the table on pp. 204, 205:
Duckering’s experiments as to the presence of fumes containing
compounds of lead in the atmosphere breathed were carried out in a
workshop for the tinning of iron hollow-ware with a mixture consisting
of half lead and half tin. The process of manufacture and the main
sources of lead contamination in the air (knowledge arrived at from
these experiments) are explained on p. 59. As the result of laboratory
experiments designed to show the effect of the violent escape of vapour
produced below the surface of molten metal in causing contamination of
the air, and the nature of the contaminating substances, he was able
to conclude that the chemical action of the materials (acid and flux)
used, and subsequent vaporization of the products of this action, was
a much more important factor than the mechanical action of escaping
vapour. Subsequently, experiments carried out on factory premises gave
the results which are expressed in the table as to the relative danger,
from lead, to (_a_) a tinner using an open bath; (_b_) a tinner working
at a bath provided with a hood and exhaust by means of a furnace flue;
and (_c_) the nature and extent of air contamination caused by the
operation of wiping excess of metal (while still in a molten state)
from the tinned article. In all three experiments aspiration of air
was made slowly: it was maintained at the rate of 3 to 4 cubic feet
an hour in the first experiment for between seven and eight hours; in
the second for twenty-eight to twenty-nine hours; and in the third for
twenty-four to twenty-five hours. The person engaged in tinning at the
open bath was shown to be exposed to much more danger than one working
at a hooded bath, while the wiper was exposed to even more danger than
the tinner using an open bath, since not only was he inhaling fume from
the hot article, but also fibre to which considerable quantities of
metallic lead and tin adhered.
Analysis of samples of dust collected in different parts of the
workroom bore out the conclusions derived from analysis of the
fumes. Thus, samples collected from ledges at varying heights above
the tinning bath containing the mixture of tin and lead contained
percentages of soluble lead (lead chloride) in striking amount as
compared with samples collected at points in the same room remote from
any source of lead fume, while the insoluble lead present, as was to be
expected from the fact that it consisted of lead attached to particles
of tow floating in the air, was less variable.
TABLE XII., SHOWING QUANTITIES OF LEAD (PB) IN THE ATMOSPHERE AT
BREATHING LEVEL.
(G. E. DUCKERING’S EXPERIMENTS.)
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