Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving riskLegge, Thomas Morison, Sir
Science
Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving risk
Legge, Thomas Morison, Sir
Lead poisoning
=Spelter (Zinc) Manufacture.=--Lead is present in zinc ores in a
proportion of from 1 to 10 per cent. (usually 3 per cent.). Despite
this small proportion, incidence of chronic plumbism among those
engaged in the manufacture is high, as in the present state of
knowledge the lead fume given off in distillation of the zinc cannot
be efficiently removed. Blende (zinc sulphide) is first calcined, and
the residue, after mixture with calamine (zinc ashes) and anthracite,
forms the charge for the furnace. The retorts are arranged in long
rows one above the other, and frequently back to back in the furnace,
so that there may be 250 or more to each furnace, and of the furnaces
there may be several in a shed. Attached to the retort is a fireclay
receptacle (condenser) into which the zinc distils, and an iron nozzle
(prolong) to prevent oxidation in the condenser. While distillation
goes on the carbonic oxide gas evolved burns brightly, tinged with the
greenish-white colour imparted by the zinc. The products of combustion,
with traces of lead fume from the hundreds of prolongs, are discharged
into the atmosphere of the sheds, where temperature is high. The
latest design of prolongs, however, has an exit at which the products
of combustion escape near the furnace, so that the greater portion
pass up into the ventilating hoods. Periodically--three times to each
charge--the workman removes the prolong, ladles out such zinc as has
condensed, and pours it into moulds. Finally, when distillation is
completed, the contents of the retorts are raked out, and it is in the
fuming hot residues so deposited on the floors that much of the danger
arises. In distilling furnaces of modern design the hot residues fall
through openings in the window of the furnaces into “pockets,” in
which they cool off considerably before they are drawn out into iron
skips. In another form of furnace used in the manufacture of spelter
(Silesian), the workman after charging can leave the furnace until the
time for tapping arrives. The two operations involve work for six hours
a day only.
_Dangers and Prevention._--During distillation the detrimental effect
of a current of air (formation of zinc oxide) on the zinc is an
obstacle to the removal of the fume by exhaust ventilation locally
applied over the prolongs of the condensers. Exhaust ventilation of
a kind can, however, be arranged, except under unfavourable weather
conditions, by erecting hoods of material such as galvanized iron right
across the roof of the shed over, and parallel with, the furnaces, up
which the heated current of air from the furnaces travels. Lofty, roomy
sheds assist materially in the escape of the fumes. Various forms of
modification in the condensers, designed to lessen escape of fume, and
so recover more zinc, are being tried.
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