Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving riskLegge, Thomas Morison, Sir
Science
Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving risk
Legge, Thomas Morison, Sir
Lead poisoning
_Manufacture of Terne Plates._--The manufacture of lead-coated sheets
for roofing purposes is carried on in a few works in South Wales along
with the manufacture of tin plates. Lead poisoning in the industry
is practically unknown. We can only recollect occurrence of one
case, despite the fact that the mixture contains from 65 to 95 per
cent. of lead. For cleaning the plates prior to passing them through
the concentrated zinc chloride flux into the molten mixture, dilute
sulphuric acid is used, and not hydrochloric acid. As to the remarkably
different results on health of the two processes, Duckering concludes:
“The absence of lead poisoning among terne-plate workers and tinners
would appear to be explained by--(1) The use of cleaning agents and
a flux of such a nature, and in such a way, as to involve a minimum
contact with the tinning metals, and under such conditions as to
inhibit extensive interaction between them, and also under such
conditions as to inhibit production of fume or vapours, even if
any interaction occurs; (2) use of a scientifically prepared flux
containing no uncombined acid or excess of water in such a way as to
prevent introduction of these substances, or of ferrous compounds
coming into intimate contact with the tinning metal; (3) so conducting
the operation of tinning that any chlorides possibly adhering to the
plates are removed before the plate reappears in the open air, under
conditions preventing them from appearing in the air as vapour, but
it is very doubtful whether any chlorides could adhere to the plates;
and (4) absence of any manual work on the plates before the metallic
coating is set and hard. On the other hand, the existence of widespread
lead poisoning in tinning of hollow-ware is explained by--(1) Use of
cleaning agents and flux in such a way as to bring these materials into
intimate contact with the tinning metals under conditions eminently
favourable to chemical interaction and vaporization of resultant
compounds; (2) use of an unscientifically prepared flux containing
a large excess of water and much free acid; (3) so conducting the
operations as to favour the escape into the atmosphere of vapours of
soluble lead compounds, such as lead chloride, and of metallic lead and
soluble lead compounds, carried mechanically by fibres of tow during
processes subsequent to tinning, as in wiping; and (4)--a minor point
not to be lost sight of--possibility of contamination of the hands by
soluble lead compounds, due to manipulating the material with which the
articles are wiped.
“It should be added that while use of a scientifically prepared
flux [(2) above] in hollow-ware tinning would no doubt lessen the
possibility of the production of fumes, it is not to be anticipated
(unless a flux containing no chlorides were used) that this would do
away with lead poisoning. In other words, the method of use is, as
indicated above, a far more important factor.”
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