Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving riskLegge, Thomas Morison, Sir
Science
Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving risk
Legge, Thomas Morison, Sir
Lead poisoning
White enamel powders free from lead are used entirely by some firms,
but the black and coloured enamels on stove grates contain lead. A frit
analyzed in the Government Laboratory was found to contain 26·66 per
cent. of lead oxide. The fact that all the lead used is in the form of
a silicate, even although the silicate is readily soluble in dilute
acid, tends, we believe, to cause incidence of poisoning to be less
than might have been expected from the amount of dust often present in
the air, and attacks, when they occur, to be less severe, as a rule,
than they would be were raw carbonate of lead alone used. For the
arduous work entailed the men are specially selected. Despite their
exposure to lead dust, the majority continue to work for many years
without marked signs of lead absorption. The management should provide
a suitable room for the men to cool themselves in the intervals of
dusting.
[Illustration: FIG. 14.--The cabinet is shown when dry dusting is being
done. The casting is worked by tongs through a slot in the side of the
cabinet (not seen), while the worker dusts the casting with his arms
through the two front holes. He can see his work through the square
pane of glass. (Photographs kindly made by Mr. F. W. Hunt, Leeds.)]
=Manufacture of Electric Accumulators[30].=--Electric accumulators
are secondary batteries which serve for the storage of electricity,
in order to allow of a current when desired. A primary battery is
one in which the materials become exhausted by chemical action, and,
unless a portion or the whole of the materials is renewed, fails to
supply electricity. The secondary battery becomes exhausted in the
same way, but the chemical contents are of such a nature that it is
merely necessary to pass a current of electricity through the battery
(charging) in order to recharge them. In the accumulator battery the
positive element is peroxide of lead, and the negative element spongy
lead. The elements--several positive connected together and several
negative--are placed in dilute sulphuric acid contained in vessels of
glass.
The form of accumulator in almost universal use now is the pasted
plate, but it varies greatly in size, according to the use for which
it is required. It may be either large, to act as an equalizer or
reservoir of current in electric-lighting installations, or quite small
for ignition purposes in motor-cars. The litharge smeared on to one
plate becomes converted into the positive element, peroxide of lead,
during what is called the “forming process” (passage of the electric
current through the dilute sulphuric acid solution in which it is
placed), and red lead smeared on to the other becomes spongy lead to
form the negative.
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