Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving riskLegge, Thomas Morison, Sir
Science
Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving risk
Legge, Thomas Morison, Sir
Lead poisoning
=Use of Leadless Paints.=--Opinion still differs as to the feasibility
of substituting zinc sulphide or zinc oxide (or a combination of the
two) for white lead in paints, in spite of elaborate investigation of
the point by commissions of inquiry appointed notably by the French,
Austrian, and Dutch Governments. There is, however, general consensus
of opinion that for the painting of internal surfaces of houses and
of all surfaces which are not exposed to the weather zinc paints have
the advantage (apart from their non-poisonous quality) over white-lead
paint of not changing colour. The technique for applying zinc oxide
paint differs much from that for applying white lead. Being much less
dense, it requires to be ground with a greater proportion of oil, and
the vehicles and driers necessary for the thinning of the stiff paste
are different from those ordinarily used for thinning and mixing white
lead. Coats of zinc oxide should be applied as thin as possible, and
hence there is the drawback that where three coats of white lead will
suffice, four coats of zinc oxide may be necessary unless the paint
is skilfully applied. The best method of applying zinc oxide paint
with the brush has to be learnt in order to get the best effect. The
ordinary house-painter, therefore, accustomed to the use of lead paint,
cannot expect to obtain the same result from zinc paint treated in the
same way. And zinc oxides differ in value as pigments according to the
methods of production. That obtained by direct roasting of the ore
(franklinite and zincite) is superior to that prepared by the indirect
method of oxidation of spelter.
Zinc sulphide enters into the composition of many white paints mixed
with zinc oxide, barytes, and often lead sulphate. Its defect in
colour is thus concealed, and it adds to the mixture the important
property known to the painter as “body.” Under a variety of names,
such as “Orr’s enamel white,” “patent zinc white,” and “lithopone,”
such mixtures have a large sale, and for many purposes can act as a
substitute for white-lead paint.
Extensive inquiries have been made in recent years in Continental
countries into the effect of use of white-lead paint in producing
plumbism, the processes employed, and the possibility of
substitutes--in Austria, from 1904 to 1907; in Germany, in 1905;
in Holland, from 1903 to 1909; in France, from 1901 to 1909; in
Switzerland, in 1904; and in Belgium, from 1904 to 1909. In 1902
the French Government, by a decree applying to house-painting,
prohibited (1) use of white lead except when ready mixed with oil; (2)
direct handling of white lead; (3) dry-rubbing or sand-papering of
painted surfaces; and required (4) provision of the usual means for
cleanliness, including overalls. This decree in 1904 was extended to
all kinds of painting with use of white lead. Finally, in 1909, a law,
to take effect from 1914, was passed prohibiting the use of white lead
in paint altogether.
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