Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving riskLegge, Thomas Morison, Sir
Science
Lead poisoning and lead absorption : $b The symptoms, pathology and prevention, with special reference to their industrial origin, and an account of the principal processes involving risk
Legge, Thomas Morison, Sir
Lead poisoning
=Heading of Yarn dyed with Chromate of Lead.=--Cotton yarn is dyed (10)
on a considerable scale with chromate of lead, chiefly for Oriental
markets; and it is the orange chrome--that most heavily weighted with
lead--which is most in demand there. The orange chrome colour is
obtained by dipping hanks of yarn into solution of lime, and then into
acetate of lead. The process is repeated a second time, after which
the chromate is formed by dipping in bichromate of soda, and finally
boiling in lime-water[39].
In production of yellow chrome colour, the yarn is treated only once
in a bath of lead acetate. Other colours made are lemon chrome and (by
addition of an indigo bath) chrome green.
The early processes of dyeing rarely give rise to poisoning, but the
strong solution of bichromate of soda readily causes characteristic
ulceration of the skin--“chrome holes.” Danger arises from dust in
the process of heading or “noddling,” as it is sometimes called, of
the dried yarn over posts. The hanks of yarn are tugged and shaken by
women as a rule, and in the case of orange chrome very considerable
quantities of dust are liberated. We have been told that a hank of this
kind of yarn does not commend itself to an Oriental buyer unless, when
shaken, dust is visible.
The industry was certified as dangerous in 1895, in view of serious
illness and death in Glasgow and Manchester, and special rules were
made to apply, not only to the heading operations, but also to the
winding, reeling, and weaving, of the dyed yarn--processes in which
cases of poisoning are very rare.
Detailed inquiry was made in 1906 in eleven factories where yarn was
dyed on a considerable scale by means of chromate of lead--in eight
mainly for export to India, and in three for the home market. Yarn dyed
for the home market gives off less dust when headed, as the material
undergoes additional washing in water and in dilute acid; and it is
also sometimes passed through a sizing of starch, which fixes the
chromate of lead to the yarn more securely.
Proof of the greater danger from orange chrome is found in the fact
that Dupré was able to wash 1 pound of dust (0·29 per cent.) from 345
pounds of heavy orange yarn, and only 1 pound (0·03 per cent.) could be
washed from 3,300 pounds of light yellow or green yarn.
In none of the factories were the workers engaged solely on the
dangerous yellow and orange chrome-dyed yarn. In some the work may
last an hour or two every day, in others for an hour or two every day
in alternate weeks, or for one week in every three or four weeks, and
perhaps in a dozen factories the work may not be done more frequently
than half a day a month, or even one in three months.
Public-domain text, read in full here on John Shaqi.
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