Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
When the operation in the pot is completed, the latter is turned on its
trunnions, until the charge slides out by gravity, which it does as a
solid cake. This is caused to fall upon a vertical bar, which breaks
it into large pieces. By wedging and sledging these are reduced to
lumps of suitable size for the blast furnace. When the operation has
been properly conducted the charge is reduced to about 2 or 3 per cent.
sulphur. It is expected that the use of larger converters will show
even more favorable results in this particular.
As in the Huntington-Heberlein and Carmichael-Bradford processes, one
of the greatest advantages of the Savelsberg process is the ability to
effect a technically high degree of desulphurization with only a slight
loss of lead and silver, which is of course due to the perfect control
of the temperature in the process. The precise loss of lead has not yet
been determined, but in the desulphurization of galena containing 60
to 78 per cent. lead, the loss of lead is probably not more than 1 per
cent. There appears to be no loss of silver.
The process is applicable to a wide variety of lead-sulphide ores. The
ore treated at Ramsbeck contains 60 to 78 per cent. lead and about
15 per cent. of sulphur, but ore from Broken Hill, New South Wales,
containing 10 per cent. of zinc has also been treated. A zinc content
up to 7 or 8 per cent. in the ore is no drawback, but ores carrying a
higher percentage of zinc require a larger addition of silica and about
5 per cent. of iron ore in order to increase the fusibility of the
charge. The charge ordinarily treated at Ramsbeck is made to contain
about 11 per cent. of silica. The presence of pyrites in the ore is
favorable to the desulphurization. Dolomite plays the same part in
the process that limestone does, but is of course less desirable, in
view of the subsequent smelting in the blast furnace. The ore is best
crushed to about 3 mm. size, but good results have been obtained with
ore coarser in size than that. However, the proper size is somewhat
dependent upon the character of the ore. The blast pressure required in
the converter is also, of course, somewhat dependent upon the porosity
of the charge. Fine slimes are worked up by mixture with coarser ore.
In making up the charge, the proportion of limestone is not varied
much, but the proportions of silica and iron must be carefully modified
to suit the ore. Certain kinds of ore have a tendency to remain
pulverulent, or to retain balls of unsintered, powdered material.
In such cases it is necessary to provide more fusible material in
the charge, which is done by varying the proportions of silica and
iron. The charge must, moreover, be prepared in such a manner that
overheating, and consequently the troublesome fusion of raw galena,
will be avoided.
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