Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
The precipitation of flue dust is effected in a brick condensing
chamber, placed near the beginning of the main flue. The main flue
terminates on the hill (see Fig. 43) in a chimney, the top of which
is 160 m. above the ground level of the works, affording excellent
draft. The condensing chamber (Figs. 49 to 51) consists of a vaulted
room, 3.40 m. wide and 6.60 m. long, which is divided into twelve
compartments by one longitudinal and five baffle walls. The gases
change direction seven times, and pass over the longitudinal wall
six times, being struck six times by fine sprays of water. The six
atomizers for this purpose consume 1.5 liter of water per minute, of
which four-fifths is vaporized, while one-fifth flows off to the lower
water basin. By this means 10 to 15 per cent. of the total flue dust
is precipitated in the condensing chamber itself, and is removed from
time to time as mud through the lower openings, which are water-sealed.
The remainder of the volatilized water precipitates the flue dust
almost completely on the way to the stack, so that only a short column
of steam is visible at the mouth of the stack. The flue to the stack
passes for the most part underground through abandoned adits and
galleries, thus providing a variety of changes in cross-section and
in direction, and assisting materially the action of the condensing
chamber.
[Illustration: FIG. 47.—Section of Lead Refinery.]
[Illustration: FIG. 48.—Softening Furnace.]
As the charge of the shaft furnaces is poor in sulphur, no real matte
is produced, but only work lead and lead ashes (Bleischaum), which
contains 90 per cent. of lead, 1.6 per cent. sulphur, 0.4 per cent.
zinc, 0.85 per cent. Cu, 0.99 per cent. Fe, and 0.22 per cent. Sb. By
liquation and a reducing smelt in a reverberatory furnace, most of the
lead is obtained, along with a lead-copper matte, which is smelted for
copper matte and antimonial lead in the blast furnace.
[Illustration: FIG. 49.—Fume Condenser. (Section A B.)]
The copper matte, containing 18 per cent. Cu, 25 per cent. Fe, 30 per
cent. Pb and 18.4 per cent. S, is roasted dead in a reverberatory
furnace, is sintered, and melted to copper-bottoms in a small shaft
furnace. These copper-bottoms, which contain 60 per cent. copper and
25 per cent. lead, are subjected to liquation, and finally refined to
blister copper.
The zinc-desilvering plant, Fig. 47, consists of a reverberatory
softening furnace, two desilvering kettles of 14 tons capacity, a pan
for liquating the zinc crust, and a small kettle for receiving the lead
from the liquation process.
This pan has the advantage over the ordinary liquating kettle, that the
lead which drips off is immediately removed, before it can dissolve the
alloy; the silver content of the liquated lead is scarcely 0.05 per
cent., while the dry alloy contains 5 to 8 per cent.
[Illustration: FIG. 50.—Fume Condenser. (Section E F G H.)]
[Illustration: FIG. 51.—Fume Condenser. (Section C D.)]
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