Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
Should both nitric and sulphuric acids fail to cause a
reaction, the alkaloid is dissolved in ether,
precipitated by an ethereal solution of oxalic acid,
and the precipitate treated with a little water. If it
dissolves, it probably consists of _papaverine_.
CARBONIC ACID DISSOLVES THE ALKALOID.
The substance is treated with ether, notice being taken if it dissolves,
which is evaporated at the ordinary temperature of the air so as to
prevent a loss of minute portions of the alkaloid.
_Ether dissolves the alkaloid._--If nitric acid gives
first a scarlet, then a yellow color, sulphuric acid a
yellow, changing to red and violet, and hydrochloric
acid a violet color, the alkaloid present is probably
_veratrine_.
If the above colorations are not produced, chlorine
water is added to another portion of the substance,
then ammonia; the formation of a green color, changing
to violet and turning red upon a renewed addition of
chlorine water, denotes the presence of _quinine_.
In case all of these tests give but negative results,
and the alkaloid is soluble in concentrated sulphuric
acid, a solution being formed which assumes a
reddish-violet tint when stirred with a glass rod
previously dipped in bromine water, the presence of
_delphine_.
is indicated.
_Ether fails to dissolve the alkaloid._--If the
substance is capable of being sublimed,[N] it consists
of _cinchonine_.
[N] Cinchonine, when sublimed, condenses in minute brilliant
needles.--_Trans._
_b. Ammonia produces a precipitate, which redissolves in an excess of
the precipitant, but separates out after the lapse of an hour._
The substance is treated with cold absolute alcohol
and its solubility in this menstruum noted. If it
readily dissolves, it probably consists of _brucine_.
The presence of this alkaloid is confirmed by applying
the following tests: (1) Nitric acid imparts a
blood-red color to the substance; (2) if treated with
sulphuric acid, it acquires a reddish tint which
subsequently changes to yellow and green; (3) chlorine
at first fails to cause a coloration, but after some
time a yellow color which afterwards changes to a red
is produced; (4) upon treating the substance with
bromine, it immediately assumes a violet tinge.
In case the alkaloid is only slightly soluble in
alcohol, there is reason to infer the presence of
_strychnine_.
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