Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
The following confirmatory tests should be applied:
(1) If the substance is treated with a mixture of
sulphuric acid and an oxidizing body, such as
bichromate of potassa, binoxide of manganese, or
peroxide of lead it acquires a violet color, which
changes into red and finally passes into a clear
yellow; (2) the addition of bichloride of platinum
produces a precipitation of the hydrochlorate.
Should, however, the substance be only slightly soluble
in alcohol, and the above reactions fail to take place,
the presence of _solanine_.
is indicated. In presence of this alkaloid the following
reactions will occur: (1) Upon treating the substance
with concentrated sulphuric acid, it assumes a rose
tint, which changes after some time has elapsed first to
a deep violet, then to a brown color; (2) a solution of
a salt of the alkaloid reduces gold and silver salts;
(3) the addition of oxalic acid produces a precipitate
in the aqueous and even acid solution of its salts.
_c. Ammonia fails to produce a precipitate, or redissolves permanently
the one formed._
The solubility of the alkaloid in ether is ascertained. If it be
soluble, it may consist of aconitine, atropine or codeine; if insoluble,
of emetine or morphine.
_The alkaloid is soluble in ether._--If bichloride of
platinum fails to precipitate the hydrochlorate from a
neutral solution of the alkaloid, and sulphuric acid
causes it to assume a yellow color which subsequently
changes to a reddish-violet, it probably consists of
_aconitine_.
In case bichloride of platinum causes a precipitate
and sulphuric acid fails to produce the yellow
coloration referred to above, the presence of either
atropine or codeine is indicated. In order to decide
which of these bases is present, the substance is
dissolved in pure chloric acid and the solution allowed
to spontaneously evaporate. If the alkaloid is
deposited during this operation, it probably consists
of _atropine_.
If this is not the case, there is reason to infer the
presence of _codeine_.
_The alkaloid is insoluble in ether._--If it dissolves
in acetone it probably consists of _emetine_.
If acetone fails to dissolve it, the presence of
_morphine_.
is indicated.
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