Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
_Linseed and rye meals._--If linseed meal is moistened with an aqueous
solution containing 14 per cent. of potassa and examined under the
microscope, numerous minute characteristic granules, smaller than the
grains of potato-starch, are observed. These possess a vitreous
appearance, sometimes a reddish color, and usually form in squares or
very regular rectangles. The test is equally applicable to bread. The
detection of linseed and rye meals is simultaneously effected by
exhausting the suspected flour with ether, then filtering the solution
and allowing it to evaporate. If the flour contains rye, the oil left by
the evaporation, when heated with a solution of mercury in concentrated
nitric acid, is converted into a solid substance having a fine red
color; but it remains unaltered, if entirely due to linseed. In case the
oil becomes solidified, the mercury salt present should be removed by
washing with water, the residue taken up with boiling alcohol of 36° B.
and the solution filtered: upon evaporating the alcoholic filtrate, a
residue is obtained consisting of the linseed oil present.
_Buckwheat._--Flour adulterated with buckwheat is less soft to the
touch, does not pack as easily, and passes more readily through a sieve
than pure wheaten flour. It presents, here and there, blackish
particles, due to the perisperm of the grain, and has a dirty-white
color. As previously remarked, the gluten obtained from a mixture of
buckwheat and wheaten flour possesses a grey or even a black color. The
starch furnished by buckwheat flour exhibits polyhedral agglomerations,
analogous to those presented by corn.
_Darnel._--The use of darnel in the adulteration of wheaten flour may
give rise to serious sanitary results. To effect its detection, the
flour to be examined is digested with alcohol of 35° B.: if the flour be
pure, the alcohol remains limpid: it acquires a straw-yellow tint, due
to traces of bran present, but--although a peculiar resin may be
dissolved--the solution does not possess a disagreeable taste. When, on
the contrary, darnel is present, the alcohol assumes a green tint, which
gradually deepens, and possesses a bitter and nauseous taste; the
residue, left by the evaporation of the tincture to dryness, has a
greenish-yellow color, and a still more disagreeable flavor than the
alcoholic solution.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account