Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
_a._ The density of the oil is determined by means of a hydrometer
(_oleometer_) provided with a scale giving the densities from 0.8 to
0.94, for the temperature of 15.° Pure olive oil possesses a specific
gravity of 0.917; poppy oil one of 0.925; a mixture of the two, an
intermediate density. Since the fixed oils are not definite chemical
compounds, this test is seldom conclusive.
_b._ Two or three cubic centimetres of concentrated nitric acid,
containing nitric peroxide in solution (or a solution of mercury in
strong nitric acid), are added to the oil to be examined, as well as to
a sample of pure olive oil. The two samples are then allowed to stand in
a room where the temperature does not exceed 10.° The _oleine_ of the
olive oil is converted into solid _elaidine_, and the mixture after some
time becomes sufficiently thick to remain in the vessel upon inversion.
If the sample under examination is free from adulteration, it will
solidify at the same time as the pure oil; whereas, the presence of one
per cent. of poppy oil, or of other drying oils, suffices to retard the
solidification for forty minutes.
_c._ Fifteen grammes of the oil are mixed in a glass vessel with the
same amount of strong sulphuric acid, the temperature of the two liquids
being previously observed. The mixture is stirred with a thermometer,
and the maximum temperature noted: pure olive oil produces an elevation
of temperature of 37.°7; pure poppy oil, an elevation of 70.°5; and a
mixture of the two an elevation of temperature intermediate between
37.°7 and 70.°5.
_d._ One volume of nitric acid of sp. gr. 1.33 is agitated with 5
grammes of the oil, and notice taken of the coloration produced after
the lapse of five minutes. If the olive oil is pure, it acquires a pale
green color; in case it is mixed with sesamé or nut oil, a deep-red
color appears: poppy oil also communicates a reddish coloration, but one
less deep than the preceding.
If an acid of sp. gr. 1.22 is taken, it is still less difficult to
distinguish between sesamé, nut and poppy oils; the latter assumes, in
this case, a pale yellowish-red color.
Pea-nut oil fails to exhibit a coloration; but can be recognized by its
conversion into a white solid, when mixed with 1/5 of its volume of a
solution of caustic soda of sp. gr. 1.34.
EXAMINATION OF OLIVE OIL INTENDED FOR MANUFACTURING PURPOSES.
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