Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
The presence of foreign leaves, and, in some instances, of mineral
adulterants, in tea is best detected by means of a microscopic
examination of the suspected sample. The genuine tea-leaf is
characterized by its peculiar serrations and venations. Its border
exhibits serrations which stop a little short of the stalk, while the
venations extend from the central rib, nearly parallel to one another,
but turn just before reaching the border of the leaf (see Fig. 16). The
Chinese are said to employ ash, plum, camellia, velonia, and dog-rose
leaves for admixture with tea, and the product is stated to be often
subjected in England to the addition of the leaves of willow, sloe,
beech, hawthorn, elm, box-poplar, horse-chestnut, and fancy oak (see
Figs. 17, 18, and 19). For scenting purposes chulan flowers, rose,
jasmine, and orange leaves are frequently employed. In the microscopic
examination the sample should be moistened with hot water, spread out
upon a glass plate, and then submitted to a careful inspection, especial
attention being given to the general outline of the leaf and its
serrations and venations. Most foreign leaves will, in this way, be
identified by their botanical character. The presence of exhausted
tea-leaves may also often be detected by their soft and disintegrated
appearance. If a considerable quantity of the tea be placed in a long
glass cylinder and agitated with water, the coloring and other abnormal
bodies present frequently become detached, and either rise to the
surface of the liquid as a sort of scum or fall to the bottom as a
deposit. In this way Prussian blue, indigo, soap-stone, gypsum, sand,
and turmeric can sometimes be separated and subsequently recognized by
their characteristic microscopic appearance. The separated substances
should also be chemically tested. Prussian blue is detected by heating
with a solution of caustic soda, filtering, and acidulating the filtrate
with acid, and then adding chloride of iron, when, in its presence, a
blue color will be produced. Indigo is best discovered by its appearance
under the microscope; it is not decolorized by caustic alkali, but it
dissolves in sulphuric acid to a blue liquid. Soap-stone, gypsum, sand,
metallic iron, etc., are identified by means of the usual chemical
tests. A compound, very aptly termed "Lie-tea," is often met with. It
forms little pellets consisting of tea-dust mixed with foreign leaves,
sand, etc., and held together by means of gum or starch. This, when
treated with boiling water, falls to powder. In the presence of catechu
the tea infusion usually becomes muddy upon cooling; in case iron salts
have been employed to deepen the color of the liquor, they can be
detected by treating the ground tea-leaves with acetic acid and testing
the solution with ferrocyanide of potassium. Tea should not turn black
upon immersion in hydrosulphuric acid water, nor should it impart a blue
color to ammonia solution. The infusion should be amber-colored, and not
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