Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
The water present is indirectly estimated by determining the amount of
acetic acid contained in the vinegar. This can be accomplished in
different ways: either the quantity of a standard solution of an alkali,
necessary to exactly neutralize a measured quantity of the vinegar, is
ascertained, or the vinegar is supersaturated with solution of baryta,
the excess of the salt eliminated by conducting carbonic acid through
the fluid, the precipitate removed by filtration, and the baryta salt in
the filtrate precipitated by the addition of sulphuric acid. The second
precipitate is then collected on a filter, washed, weighed, and the
amount of acetic acid present calculated: this is done by multiplying
its weight by 0.515.
SULPHATE OF QUININE.
Owing to the high price of this salt, it is frequently adulterated. The
substances used for this purpose are: crystalline sulphate of lime,
boric acid, mannite, sugar, starch, salicine, stearic acid, and the
sulphates of cinchonine and quinidine. These bodies are detected as
follows:
_a._ Upon slightly warming 2 grammes of sulphate of quinine with 120
grammes of alcohol of 21° B., the pure salt completely dissolves; if,
however, starch, magnesia, mineral salts, or various other foreign
substances are present, they are left as insoluble residues.
_b._ Those mineral substances that are soluble in alcohol are detected
by calcining the suspected sample: pure sulphate of quinine is
completely consumed; whereas, the mineral substances present remain
behind as a residue.
_c._ In presence of salicine, the salt acquires a deep red color, when
treated with concentrated sulphuric acid.
_d._ Stearic acid remains undissolved upon treating sulphate of quinine
with acidulated water.
_e._ To detect sugar and mannite, the sample is dissolved in acidulated
water, and an excess of hydrate of baryta added: a precipitate,
consisting of quinine and sulphate of baryta, is produced. Carbonic acid
is then passed through the fluid, in order to precipitate the excess of
baryta as insoluble carbonate, the fluid saturated with ammonia, to
throw down the quinine which may have been re-dissolved by the carbonic
acid, and the mixture filtered. If the salt be pure, no residue will be
obtained upon evaporating the filtrate; a residue of sugar or mannite is
formed, if these substances are present.
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