Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical JurisprudenceNaquet, Alfred
Science
Legal Chemistry: A Guide to the Detection of Poisons, Examination of Tea, Stains, Etc., as Applied to Chemical Jurisprudence
Naquet, Alfred
Chemistry, Forensic; Poisons
The tests more recently introduced consist in the production of small
characteristic crystals, termed _haemin_ crystals, and in the use of the
spectroscope. Crystals of haemin (first discovered by _Teichman_) are
formed when dry blood is dissolved in concentrated acetic acid, and the
solution evaporated to dryness: they are of a brownish-red color.
_Brücke_ first suggested an analytical method, based upon this property
of blood, which is equally characteristic and sensitive: It is only
necessary to dissolve a minute portion of the matter to be examined
(dried blood, or the residue left by the evaporation of the fluid
obtained by treating the stain, or the dried blood, with cold water) in
glacial acetic acid and evaporate the solution to dryness in order to
obtain crystals of haemin, which can be readily recognized by means of a
microscope having a magnifying power of 300 diameters. If the crystals
originate from fresh blood, they appear as represented in Fig. 21;
crystals from old blood are represented in Fig. 22.
[Illustration: Fig. 21.]
[Illustration: Fig. 22.]
The former possess a reddish-brown, the latter a lighter color.
The various methods now employed to produce haemin crystals were
proposed by _Hoppe-Seyler_, by _Brücke_ and by _Erdman_. Whichever
process is used, the suspected stains are at first carefully separated
from the material upon which they are deposited. If they are present on
linen, or other fabrics, the stained portions, which always remain
somewhat stiff, are cut off: they will present a reddish-brown color, in
case the cloth is not dyed: if the stains are on wood, they are removed
by means of a sharp knife; if on stone or iron, they are detached by
scraping.
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