Letters on Natural Magic; Addressed to Sir Walter Scott, Bart.Brewster, David
History
Letters on Natural Magic; Addressed to Sir Walter Scott, Bart.
Brewster, David
Scientific recreations
If we use a uniform and homogeneous disc of silver that has never been
hammered or compressed, its surface will oxidate equally, provided all
its parts are equally heated. In the process of converting this disc
into a coin, the _sunk_ parts have obviously been _most compressed_
by the prominent parts of the die, and the _elevated_ parts _least
compressed_, the metal being in the latter left as it were in its
natural state. The raised letters and figures on a coin have therefore
less density than the other parts, and these parts oxidate sooner or
at a lower temperature. When the letters of the legend are worn off by
friction, the parts immediately below them have also less density than
the surrounding metal, and the site as it were of the letters therefore
receives from heat a degree of oxidation, and a colour different from
that of the surrounding surface. Hence we obtain an explanation of the
revival of the invisible letters by oxidation.
The same influence of difference of density may be observed in
the beautiful oxidations which are produced on the surface of
highly-polished steel, heated in contact with air, at temperatures
between 430° and 630° of Fahrenheit.[13] When the steel has hard
portions called pins by the workmen, the uniform tint of the film of
oxide stops near these hard portions, which always exhibit colours
different from those of the rest of the mass. These parts, on account
of their increased density, absorb the oxygen of atmospheric air less
copiously than the surrounding portions. Hence we see the cause why
steel expanded by heat absorbs oxygen, which when united with the
metal, forms the coloured superficial film. As the heat increases,
a greater quantity of oxygen is absorbed, and the film increases in
thickness.
[13] See _Edinburgh Encyclopædia_, Art. STEEL, vol. xviii., p. 387.
These observations enable us to explain the legibility of inscriptions
in the dark, whether the coin is in a perfect state, or the letters
of it worn off. All _black_ or _rough_ surfaces radiate light more
copiously than _polished_ or _smooth_ surfaces, and hence the
inscription is _luminous_ when it is _rough_, and _obscure_ when it is
polished, and the letters covered with black oxide are more luminous
than the adjacent parts, on account of the superior radiation of light
by the black oxide which covers them.
By the means now described, invisible writing might be conveyed by
impressing it upon a metallic surface, and afterwards erasing it by
grinding and polishing that surface perfectly smooth. When exposed to
a proper degree of heat, the secret would display itself written in
oxidated letters. Many amusing experiments might be made upon the same
principle.
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