Their formation is also strongly influenced by light, as is well shown
by the varying intensity of colour in some yellow thalli. _Placodium
elegans_, always a brightly coloured lichen, changes from yellow to
sealing-wax red in situations exposed to the full blaze of the sun.
_Haematomma ventosum,_though greenish-yellow in lowland situations
is intensely yellow in the high Alps. The same variation of colour
is characteristic of _Rhizocarpon geographicum_ which is a bright
citron-yellow at high altitudes, and becomes more greenish in hue as it
nears the plains. The familiar foliose lichen _Xanthoria parietina_ is
a brilliant orange-yellow in sunny situations, but grey-green in the
shade, and then yielding only minute quantities of parietin. West[827]
and others have noted its more luxuriant growth and brighter colour when
it grows in positions where nitrogenous food is plentiful, such as the
roofs of farm-buildings, which are supplied with manure-laden dust, and
boulders by the sea-shore frequented by birds.
_e._ DISTRIBUTION OF ACIDS. Some acids, so far as is known, are only
to be found in one or at most in very few lichens, as for instance
cuspidatic acid which is present in _Ramalina cuspidata_, and scopuloric
acid, a constituent of _Ramalina scopulorum_, the acids having been held
to distinguish by their reactions the one plant from the other.
Others of these peculiar products are abundant and widely distributed.
Usninic acid, one of the commonest, has been determined in some 70
species belonging to widely diverse genera, and atranorin, a substance
first discovered in _Lecanora atra_, has been found again many times;
Zopf gives a list of about 73 species or varieties from which it has been
extracted. Another widely distributed acid is salazinic acid which has
been found by Lettau[828] in a very large number of lichens.
E. CHEMICAL GROUPING OF LICHEN-ACIDS
Most of these acids have been provisionally arranged by Zopf in groups
under the two great organic series: I. The Fat series; and II. The
Benzole or Aromatic series.
I. LICHEN-ACIDS OF THE FAT SERIES
=Group 1.= Colourless substances soluble in alkali, the solution not
coloured by iron chloride. Exs. protolichesterinic acid (C₁₉H₃₄O₄)
obtained from species of _Cetraria_, and roccellic acid (C₁₇H₃₂O₄) from
species of _Roccella_, from _Lecanora tartarea_, etc.
=Group 2.= Neutral colourless substances insoluble in alkalies, but
soluble in alcohol, the solution not coloured by iron chloride.
_Exs._ zeorin (C₅₂H₈₈O₄), a product of widely diverse lichens, such
as _Lecanora_ (_Zeora_) _sulphurea_, _Haematomma coccineum_, _Physcia
caesia_, _Cladonia deformis_, etc. and barbatin (C₉H₁₄O), a product of
_Usnea barbata_.
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