_Crystals of Glycerine._—We may go a step further. Let us suppose, with
L. Errera, that we have a liquid in a state of metastable equilibrium,
whose labile equilibrium is as yet unknown. This is what actually
occurs for a very widely known body, glycerine. We do not know under
what conditions glycerine crystallizes spontaneously. If we cool it,
it becomes viscous; we cannot obtain its crystals in that way. It was
not found in crystals until 1867. In that year, in a cask sent from
Vienna to London during winter, crystallised glycerine was found,
and Crookes showed these crystals to the Chemical Society of London.
What circumstances had determined their formation? We knew not then,
and we know not now. It may be observed that this case of spontaneous
generation of the crystals of glycerine has not remained the solitary
instance. M. Henninger has noted the accidental formation of glycerine
crystals in a manufactory in St. Denis.
It may be remarked that this crystalline species appeared, as living
species may have done, at a given moment in an environment in which a
favourable chance combined the necessary conditions for its production.
It is also quite comparable to the creation of a living species;
for having once appeared we have been able to perpetuate it. The
crystalline individuals of 1867 have had a posterity. They have been
sown in glycerine in a state of superfusion, and there they reproduced
themselves. These generations have been sufficiently numerous to
spread the species throughout a great part of Europe. M. Hoogewerf
showed a great flask full to the Dutch biologists who met at Utrecht
in 1891. M. L. Errera presented others in June 1899, to the Society of
Medical and Natural Sciences at Brussels. To-day the great manufactory
of Sarg & Co., of Vienna, is engaged in their production on a large
scale for industrial purposes.
Thus we are able to study this crystalline species of glycerine and to
determine with precision the conditions of its continued existence. It
has been shown that it does not resist a temperature of 18°, so that
if precautions were not taken to preserve it, a single summer would
suffice to annihilate all the crystalline individuals existing on the
surface of the globe, and thus the species would be extinguished.
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