"Sir,--I find by looking into the 'Art of Gunnery' that a 42-lb. shot
discharged at the rate of 2000 feet a second in vacuum would send it
to the height of 63,360 feet, which multiplied by the weight of the
shot would be 2,661,120 lbs., with 12 lbs. of powder; and as guns,
after being heated to about the heat of boiling water, will recoil
their usual distance with half their first charge of powder, it proves
that one-half the powder at first is lost in heating the gun to about
212°, which is a great deal under the heat of fired powder, therefore
only 6 lbs. of powder effective force is applied to the ball. Now
suppose this 6 lbs. of powder to be one quarter part carbon, 1-1/2 lb.
is all the heat that can possibly be applied to perform this duty;
then 1 lb. of carbon would be equal to 1,774,080 lbs. of duty actually
performed; but if you take into calculation the great loss of power
by the powder not being instantly all set on fire, with the gun so
much below the heat of fired powder, the windage by the sides of the
shot, the ball flying from the powder, and the immense power remaining
in the gun at the time of the ball leaving its muzzle; if this was
applied expansively, as in a cylinder, it may fairly be said to have
double this power, or 3,548,160 lbs. for 1 lb. of carbon consumed,
which, multiplied by 84, being the pounds in 1 bushel of carbon,
gives 300 millions of duty. If it was applied to the best advantage,
say on a piston, calling powder one thousand atmospheres, it would far
exceed that duty. A gun 9 feet long and 7-inch bore has 16 feet of
cold sides, and condenses at first one-half of its force by its cold
sides and loses 150 millions in a 200th part of a second, while the
ball passes from the breech to the muzzle. This gives 221,760 lbs.
condensed by each foot of surface sides in so short a time. Binner
Downs cylinder was taken as condensing 2500 lbs. for each surface
foot in six seconds; therefore, without taking into account the great
difference in time, there is eighty-eight times as much power lost
by each foot of cold sides of the gun as by the cylinder sides. This
shows what a considerable power is lost by cold sides where the vapour
is so rare. Boulton and Watt's engine, doing twenty millions, performs
with 1 lb. of coal a duty of 240,000 lbs., or about 1/14th part of
what is done by 1 lb. of carbon in powder. The water evaporated by the
boiler is 7 lbs. thrown into steam by 1 lb. of coal, and a duty of
33,750 lbs. for each pound of water evaporated.
"Suppose 1 lb. of powder to contain 12 oz. of nitre and 4 oz. of
carbon, and 1/24th part of the nitre to be a fixed water, which would
be half an ounce of water in every pound of powder, making the carbon
eight times as much as the water; from this data 1 lb. of water in
powder would perform a duty of 28,385,280 lbs.
Public-domain text, read in full here on John Shaqi.
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