Lord Kelvin: An account of his scientific life and workGray, Andrew
Science
Lord Kelvin: An account of his scientific life and work
Gray, Andrew
Kelvin, William Thomson, Baron, 1824-1907
There are several scales of temperature: in point of fact the scale of a
mercury-in-glass thermometer is defined by the process of graduation,
and therefore there are as many such scales as there are thermometers,
since no two specimens of glass expand in precisely the same way. Equal
differences of temperature do not correspond to equal increments of
volume of the mercury: for the glass envelope expands also and in its
own way. On the scale of a constant pressure gas thermometer changes of
temperature are measured by variations of volume of the gas, while the
pressure is maintained constant; on a constant volume gas thermometer
changes of temperature are measured by alterations of pressure while the
volume of the gas is kept constant. Each scale has its own independent
definition, thus if the pressure of the gas be kept constant, and the
volume at temperature 0° C. be v₀ and that at any other temperature be
v₁ we define the numerical value t, this latter temperature, by the
equation v = v₀(1 + Et), where E is 1⧸100 of the increase of volume
sustained by the gas in being raised from 0° C. to 100° C. These are
the temperatures of reference on an ordinary centigrade thermometer,
that is, the temperature of melting ice and of saturated steam
under standard atmospheric pressure, respectively. Thus t has
the value (v⧸v₀ - 1)⧸E, and is the temperature (on the constant
pressure scale of the gas thermometer) corresponding to the volume v.
Equal differences of temperature are such as correspond to equal
increments of the volume at 0° C.
Similarly, on the constant volume scale we obtain a definition of
temperature from the pressure p, by the equation t = (p⧸p₀ - 1)⧸E',
where p₀ is the pressure at 0° C., and E' is 1⧸100 of the change of
pressure produced by raising the temperature from 0° C. to 100° C.
For air E is approximately 1⧸273, and thus t = 273(v - v₀)⧸v₀.
If we take the case of v = 0, we get t = -273. Now, although this
temperature may be inaccessible, we may take it as zero, and the
temperature denoted by t is, when reckoned from this zero, 273 + t.
This zero is called the absolute zero on the constant pressure air
thermometer. The value of E' is very nearly the same as that of E; and
we get in a similar manner an absolute zero for the constant volume
scale. If the gas obeyed Boyle's law exactly at all temperatures, E
would not differ from E'.
It was suggested to Thomson by Joule, in a letter dated December 9,
1848, that the value of μ might be given by the equation
μ = JE⧸(1 + Et). Here we take heat in dynamical units, and therefore
the factor J is not required. With these units Joule's suggestion is
that μ = E⧸(1 + Et), or with E = 1⧸273 μ = 1⧸(273 + t), that is,
μ = 1⧸T where T is the temperature reckoned in centigrade degrees from
the absolute zero of the constant pressure air thermometer.
Public-domain text, read in full here on John Shaqi.
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