Lord Kelvin: An account of his scientific life and workGray, Andrew
Science
Lord Kelvin: An account of his scientific life and work
Gray, Andrew
Kelvin, William Thomson, Baron, 1824-1907
Let heat dH in dynamical measure be given to the wire while the stress S
is maintained constant, and let the extension increase from s to s + ds.
The stress S will do work ASds _on the wire_, and the work ratio will be
-ASds⧸dH. Now let the stress be increased to S + dS while the extension
is kept constant, and the absolute temperature raised from T to T + dT.
The stress ratio (as we may call it) is dS⧸S and the temperature ratio
dT⧸T. Thus we obtain (p. 134 above)
-(dS⧸dT) = (1⧸TA) (dH⧸ds)
In his Heat article Thomson used the alteration e of strain under
constant stress (that is ds⧸l, where l is the length of the wire)
corresponding to an amount of heat sufficient to raise the temperature
under constant stress by 1°. Hence if K be the specific heat under
constant stress, and le be put for ds in the sense just stated, we have
dT = -(TedS⧸Kρ) ... (F)
where ρ is the density, since dH = KρlA.
The ratio of dH to the increase ds of the extension is positive or
negative, that is, the substance absorbs or evolves heat, when strained
under the condition of constant stress, according as dS⧸dT is negative
or positive. Or we may put the same thing in another way which is
frequently useful. If a wire subjected to constant stress has heat given
to it, ds is negative or positive, in other words the wire shortens or
lengthens, according as dS⧸dT is positive or negative, that is,
according as the stress for a given strain is increased or diminished by
increase of temperature.
It is known from experiment that a metal wire expands under constant
stress when heat is given to it, and thus we learn from the equation (F)
that the stress required for a given strain is diminished when the
temperature of the wire is raised. Again, a strip of india-rubber
stretched by a weight is shortened if its temperature is raised,
consequently the stress required for a given strain is increased by
rise of temperature.
These results, from a qualitative point of view, are self-evident. But
from what has been set forth it will be obvious that an equation exactly
similar to (F) holds whether the change ds of s is taken as before under
constant stress, or at uniform temperature, or whether the change dS of
S is effected adiabatically or at constant strain.
In all these cases the same equation
dT = -T (edS⧸Kρ) ... (G)
applies, with the change of meaning of dT involved.
Public-domain text, read in full here on John Shaqi.
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