McClure's Magazine, Vol. 1, No. 6, November 1893Various
General
McClure's Magazine, Vol. 1, No. 6, November 1893
Various
American literature -- Periodicals; Literature -- Periodicals
Liquid oxygen at atmospheric pressure boils at −184° C. (−229.2°
F.). By evaporating it under a diminished pressure, he gets much
higher degrees of cold, and these have enabled him to both liquefy
and solidify nitrogen and air. The experiment illustrating this
was not only interesting; it was difficult to believe. In a double
vacuum vessel the centre of which was an open test tube, and the
second compartment a reservoir of liquid oxygen connected with an
exhaust pump, he so lowered the pressure that the oxygen boiled
tumultuously. As it did so, drops of clear liquid began to form on
the sides of the test tube and gather at the bottom. It was liquid
air, the oxygen and nitrogen of the atmosphere liquefying together at
a temperature of −197.2° (−322.9° F.). He poured some of the liquid
air into a second tube, and then showed how the nitrogen, which
liquefies at a temperature fourteen degrees below oxygen, boiled off
first. A smouldering splinter of wood held at the mouth of the tube
was extinguished. A few moments later when it was again held there,
it burst into brilliant flame. The nitrogen had all evaporated, and
the oxygen was coming off. He explained that air became solid under
pressure at −207° C. (−340.6° F.). It was a structureless glass, and
he had not determined whether or not the oxygen in it was solid or
was held suspended as a jelly. Nitrogen solidified under pressure at
−210° C. (−346° F.). It was a white crystalline substance. He had no
knowledge as yet whether oxygen crystallized in solidifying, but his
belief was that it would not.
[Illustration: THE “COMPRESSORS.”]
Concerning hydrogen, most elusive of all the gases, he had no present
expectation of attaining liquefaction. Its critical point was below
−210° C., and its boiling point −250° C. He had no means as yet of
attacking the problem. In fact, the only thermometer he was able to
use at these low temperatures was one which used hydrogen expansion
as a measure of temperature. His main reliance in measuring low
temperatures was a thermo-electric junction. Deeply interesting also
was his description of liquid ozone, that strange form of oxygen which
though identical with it in constitution is different in molecular
arrangement. He obtains twenty per cent. of ozone from liquid oxygen
by electrical stimulation, the ozone being of a very dark blue color,
as dark as concentrated indigo. It is highly unstable, a beam of light
having caused it to explode on one occasion, and its study even in
small quantities requires all the delicacy of manipulation which is
one of the special directions in which Professor Dewar as a chemist
occupies the foremost rank.
Public-domain text, read in full here on John Shaqi.
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