Medical Jurisprudence, Volume 2 (of 3)Paris, John Ayrton
Science
Medical Jurisprudence, Volume 2 (of 3)
Paris, John Ayrton
Medical laws and legislation -- Great Britain
blow-pipe, no odour is perceptible; for, in this case, the whole of the
acid will be dissipated before the copper can acquire a temperature
sufficiently exalted to deoxidize, and reduce it. If the arsenious acid
be heated on a plate of zinc, the smell will not be evolved until the
latter metal is in the state of fusion. If, instead of the foregoing
surfaces, we employ in our experiments those of gold, silver, or
platina, no alliaceous smell whatever is produced, at any temperature,
provided every source of fallacy be carefully avoided; but it deserves
particular notice, that the author has found the flame of the spirit
lamp to be in itself, capable of decomposing the arsenious acid, in
consequence, it is presumed, of the operation of its hydrogen;[220] a
fact which is very likely to betray the experimenter, as in the first
instance it did the author, into a belief that the arsenious acid does
actually yield the odour in question.
The term Arsenious _acid_ was first bestowed upon this substance by
_Fourcroy_, since it was found to possess many of the essential
habitudes of an acid; as for instance, that of combining with the pure
alkalies to saturation. It dissolves in water; but, according to
_Klaproth_, although it requires for its solution 400 parts of that
fluid, at the temperature of 60° _Fah._ it requires not more than 13, at
212°; and it moreover appears that if 100 parts of water be boiled on
the arsenious acid, and suffered to cool, it will retain 3 grains in
solution, and deposit the remainder in crystals. This fact shews the
great importance of employing boiling water in every chemical
examination of substances supposed to contain arsenic. It proves also
that a fatal dose of the poisonous mineral may be very easily
administered in any watery vehicle, a fact which was denied on the trial
of _Ogilvy_ and _Nairne_[221] by _Dr. James Scott_, who deposed that
“Arsenic would not dissolve in warm water, but almost instantly subside
to the bottom of the vessel,” although, at the same time, he
acknowledged that “if it were put into tea with milk and sugar, and
stirred about, it _might_ be suspended long enough to kill those who
should drink the potion.” It is soluble in alcohol, and in fixed oils,
the former taking up two per cent. By the addition of an alkali, an
_arsenite_ of great solubility will result, and a solution of extreme
virulence may be thus effected. With _lime-water_ arsenious acid
produces a white precipitate of _arsenite of lime_, but which is soluble
in an excess of the acid. With _magnesia_ it also forms a very soluble,
and extremely active, _arsenite_.
_Symptoms of Poisoning by the Arsenious Acid._
_Hahnemann_, in his work on Arsenic, proposes a classification of its
effects founded on their relative duration and violence, and which it is
our intention to adopt on the present occasion, without any other
alteration than that of reversing the order of the classes.
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