Medical Jurisprudence, Volume 2 (of 3)Paris, John Ayrton
Science
Medical Jurisprudence, Volume 2 (of 3)
Paris, John Ayrton
Medical laws and legislation -- Great Britain
_e._ _Sulphuretted hydrogen._ This is a very delicate test for arsenic,
producing with its solution a beautiful golden coloured liquor, which,
after a short time, lets fall a precipitate, and which will take place
sooner if a small quantity of acetic acid be added. By this re-agent so
small a quantity as 1/100000 may be detected in solution. The test,
however, is not, says _Dr. Bostock_, sufficiently discriminative to be
depended upon alone; since _tartarized antimony_ and some other bodies,
will produce phenomena that may be mistaken for the effects of arsenic.
It has, however, the merit of not being affected by _tannin_, and may
therefore be conveniently employed for precipitating arsenious acid,
when dissolved in tea.
_f._ _Lime water_ produces with the solution of arsenic a beautiful
white precipitate of _arsenite of lime_, which easily dissolves in an
excess of arsenious acid.
The precipitates occasioned by the foregoing reagents, should be
carefully collected, and treated with _black flux_, in a glass tube, for
the purpose of obtaining the metallic sublimate, as above described.
We cannot quit this part of our subject without directing the reader’s
attention to the chemical evidence given by _Dr. Addington_, on the
trial of _Mary Blandy_ (_see Appendix, p._ 241) to prove that arsenic
was contained in a powder with which she was supposed to have poisoned
her father. To those in the least acquainted with the habitudes of
arsenious acid, it must be evident, that no one of the appearances
described by _Dr. Addington_ indicates the presence of arsenic;[258] and
his evidence is only to be reconciled upon the supposition that, instead
of the arsenic itself, he, in this case, detected the foreign substances
with which it had been adulterated; thus it has been before stated that
_white arsenic_, as sold by the druggists, is often adulterated with
_sulphate of lime_; and the decomposition of this substance by the
_sub-carbonate of ammonia_ (“_Spirit of sal-ammoniac_”) or by the
_sub-carbonate of potass_ (“_Lixivium of tartar_”) would occasion the
precipitation of a white substance, as stated in the evidence; it is
however difficult to account for the “considerable precipitation of a
lightish coloured substance” by muriatic acid (_spirit of salt_) by the
presence of any impurity likely to be contained in the arsenic, or in
the water employed for its solution. If any lime were present, it would
probably give “white glittering crystals” of sulphate of lime, by the
addition of sulphuric acid (_spirits of vitriol_). The only plausible
evidence of the presence of arsenic in the suspected powder is “the
alliaceous smell and white flowers” which _Dr. Addington_ describes as
occurring when it was thrown on red hot iron; it must however be
confessed, that from the fallacy of the other experiments, it is even
impossible to place any confidence in those last mentioned.
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