Medical Jurisprudence, Volume 2 (of 3)Paris, John Ayrton
Science
Medical Jurisprudence, Volume 2 (of 3)
Paris, John Ayrton
Medical laws and legislation -- Great Britain
convince the public mind of the accuracy and truth of his researches.
2. _The Arsenious Acid is mixed with various alimentary and other
substances._
The detection of the presence of arsenic, amidst a complicated mass of
alimentary matter, has long been a problem of interest and difficulty.
In the directions which have been already offered for the discovery of
arsenic in solution, we have in some measure anticipated several of the
resources, of which we are now to avail ourselves. It has been seen how
greatly coloured fluids are capable of obscuring, and changing, and even
altogether preventing, the arsenical indications. _M. Orfila_, with an
assiduity and accuracy which so eminently characterise all his
toxicological labours, has accordingly investigated the peculiar
appearances assumed by the arsenical precipitates in different media,
such as bile, tea, coffee, wine, broth, jelly, &c. Since the publication
of the great work[260] in which these phenomena are recorded, its author
has proposed a new method[261] of removing its difficulties and
embarrassments, occasioned by the colouring matter of the above media;
which consists in a previous application of _Chlorine_, so as to change
the colour to a shade, that will not offer any optical impediment to the
characteristic indications of the tests in question. We are ready to
admit that such a mode of proceeding may, on certain occasions, assist
the accomplished chemist in his analysis; but in the hands of a person
less accustomed to chemical manipulation, we hesitate not to declare
that it is subject to fatal fallacies; whereas, by collecting the
precipitate, and submitting it to the process of sublimation we shall at
once obtain the arsenious acid in a pure form, and be enabled to test
it, in distilled water without the chance of error. Why then should we
attempt to pursue our game through the windings of a labyrinth, when a
direct road lies before us by which we may drive it into the open plain?
We accordingly recommend the juridical chemist, who suspects the
presence of arsenious acid in broth, coffee, or any coloured liquid, to
add a solution of _ammoniuret of silver_, and thus to precipitate
indiscriminately all the bodies which it may be capable of so affecting.
The precipitate may then be collected, and submitted to heat in a glass
tube, as before directed.
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