Medical Jurisprudence, Volume 2 (of 3)Paris, John Ayrton
Science
Medical Jurisprudence, Volume 2 (of 3)
Paris, John Ayrton
Medical laws and legislation -- Great Britain
of the metal may be obtained, by drying it upon a filter, mixing it with
an equal bulk of potass, and melting it in a small glass tube.
This complicated mode of proceeding will rarely be found necessary; but
it should not be neglected, where the presence of arsenic cannot be
otherwise detected in the alimentary canal of those who are suspected to
have died from its ingestion, especially in the examination of a body
where, from the length of time it may have been under ground, there is
reason to suppose that the acid exists in a state of intimate
combination with the animal matter. And we may take this opportunity to
observe, that advanced putrefaction, however disagreeable it may render
such researches, will not, in the case of arsenic, defeat their success;
let the forensic physician, then, remember, that the length of time
which may have elapsed since the death of the body, ought never to be
urged as a plea for not having proceeded in its dissection. The task may
be personally disagreeable, but it will be less painful than the
reflections which must attend a breach of duty; upon such an occasion we
would address the anatomist in the quaint but expressive words of
_Teichmeyer_[262], “_Præstat enim manus quam conscientiam cruentare et
contaminare._”
ARSENIC ACID, and ITS SALTS.
It has been stated, that the Metal Arsenic is susceptible of two degrees
of oxidizement, the result of its first degree being Arseni_ous_ acid,
and that of its second Arsen_ic_ acid. This latter compound, of which we
are now to treat, may be obtained by the repeated distillation of white
arsenic with nitric acid. In a solid state it is white, not
crystallizable; of a sour, and at the same time, metallic taste; its
specific gravity is 3·391; when exposed to the action of heat in a close
vessel, it does not become volatile, but melts and vitrifies; thrown on
burning coals, it swells, parts with its water, and becomes opaque; if
the process of deoxidation be continued, it will, at length, rise in
vapours, like those of arsenious acid, and which, like them, will yield
an alliaceous odour, or not, according to the circumstances already
explained. The _Arsenic acid_ dissolves very readily in water, and is
even indeed deliquescent. With alkalies, earths, and oxides, it
constitutes a class of salts, called “_Arseniates_,” all of which, as
well as the pure acid, are extremely active poisons; fortunately,
however, they are not much employed[263] in this country, and are not
likely to become the instruments of crime. These salts, like those of
the arsenious acid, are obedient to the different re-agents which were
enumerated under the consideration of this latter substance, but with
different results; thus the _silver_ test, instead of producing the
yellow indication, occasions an equally characteristic precipitate of a
red, or brick colour. The ammoniuret, and acetate of copper, furnish a
bluish-white precipitate. The arsenic acid, in a solid form, or the
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account