Medical Jurisprudence, Volume 2 (of 3)Paris, John Ayrton
Science
Medical Jurisprudence, Volume 2 (of 3)
Paris, John Ayrton
Medical laws and legislation -- Great Britain
According to _Thenard_,[298] antimony is susceptible of no less than six
different degrees of oxidation; _Proust_, however, has shewn that they
may all be reduced to two, viz. _protoxide_ and _peroxide_. The former
of which alone exerts any sensible activity upon the human body; but
this constitutes the basis of several preparations, which although in
common use for medical purposes, are so extremely poisonous in larger
doses, as to render them objects of interest to the forensic physician.
EMETIC TARTAR.[299] _Tartarized Antimony._
This saline body appears in the state of white crystals, whose primitive
figure is the regular tetrahedron, although it assumes a variety of
secondary forms. Its chemical composition is still involved in some
obscurity; it is stated, in the different dispensatories, to be a triple
salt, consisting of tartaric acid, oxide of antimony, and potass, and
that it ought therefore, according to the principles of the reformed
nomenclature, to be termed a _Tartrate of Antimony and Potass_. The
truth of these views, however, we have already[300] ventured to
question; _Gay Lussac_ has stated that in the various metalline
compounds of which _Super-tartrate of Potass_ is an ingredient, this
latter substance acts the part of a simple acid; an opinion which
receives considerable support from the great solvent property of _cream
of tartar_, and from the striking fact that it is even capable of
dissolving various oxides which are insoluble in tartaric acid, of which
the protoxide of antimony is an example. In such a state of doubt, a
better name could not be found than that of _tartarized antimony_.
The salt, according to _Dr. Duncan_, is soluble in three times its
weight of distilled water at 212° _Fah._ and in fifteen, at 60°.
When it is heated red hot in an earthen crucible, it blackens, and
undergoes decomposition like a vegetable body, leaving a residuum of
metallic antimony, and slightly carbonated potass.
_Symptoms of Poisoning by Emetic Tartar._
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