Medical Jurisprudence, Volume 2 (of 3)Paris, John Ayrton
Science
Medical Jurisprudence, Volume 2 (of 3)
Paris, John Ayrton
Medical laws and legislation -- Great Britain
_Organic Lesions discovered on Dissection._
Where death has been speedily produced by a cupreous poison, dissection
will generally discover inflammation, and even gangrene in the mucous
membrane of the alimentary canal. Like other poisons of the corrosive
class it will also be found to have occasionally extended its
inflammatory action to all the coats of the canal, producing sloughs,
easily detached, and leaving perforations. _Dr. Male_ has also remarked
that inflammation will sometimes be observed in the brain; but that this
is not an universal effect of copper poison. It has been stated, that
the fluids contained in the _primæ viæ_ are, upon these occasions, very
frequently tinged with a green colour.
_Chemical Tests by which the presence of the preparations of Copper may
be detected._
1. _The suspected body is in a solid form._—We have already pointed out
the characters by which the principal preparations of copper may be
identified. Our judgment, however, upon these occasions will require
that confirmation from experiment, which the following processes are
calculated to afford.
A. _By its reduction to a metallic state._ If the copper presents itself
in the form of an oxide, it may be easily reduced by heating it, in the
usual manner, in contact with some carbonaceous matter; an earthen
crucible will furnish the most convenient vessel for the occasion. If
the substance has been scraped from a surface of copper, it is probably
in the state of carbonate, (_natural verdegris_,) and may be calcined
with charcoal in order to procure the metal. Should the substance in
question be true _ærugo_, we may at once heat it to redness in an
earthen crucible, when, without the aid of any carbonaceous matter, we
shall obtain metallic copper.
B. _By the application of certain reagents, or tests, to its solutions._
It may happen that the quantity of the above substances is not
sufficient to allow their metallic reduction by calcination. In that
case, we must proceed to obtain a solution; but since neither the oxide,
nor the carbonate, is soluble in water, it will be necessary to bring
them in contact with concentrated acetic acid, so as to obtain an
acetate of copper; which will furnish the following indications with the
respective tests.
_a._ _A surface of clean iron._ If dipped into the solution will become
coated with metallic copper, and appear as if transmuted into that
metal.
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