Memoirs of Dr. Joseph Priestley : $b To the year 1795, written by himself: with a continuation, to the time of his decease, by his son, Joseph Priestley: and observations on his writings, by Thomas Cooper, President Judge of the 4th. district of Pennsylvania: and the Rev. William Christie.Priestley, Joseph
Religion
Memoirs of Dr. Joseph Priestley : $b To the year 1795, written by himself: with a continuation, to the time of his decease, by his son, Joseph Priestley: and observations on his writings, by Thomas Cooper, President Judge of the 4th. district of Pennsylvania: and the Rev. William Christie.
Priestley, Joseph
Chemists -- Great Britain -- Biography; Priestley, Joseph, 1733-1804
It did not appear that the addition of acids, enabled the water to
yield more air, nor did he succeed in attempting to convert the whole
of a given quantity of water into air, although exposing the water
confined over mercury to heat, and separating the air produced, it
still continued to produce more air for twenty or thirty repetitions
of the experiments. When a certain proportion of air was thus produced
at any one time, no continuance of the experiment would encrease the
quantity until it was separated. Hence he concludes that the longest
continuance of water in the state of vapour would not convert it
into air. The water used was pure distilled water previously boiled to
separate any adventitious air that might have been imbibed from the
atmosphere. The precautions he used, and the replies to such objections
as he foresaw the experiment would be liable to, are detailed in
the papers he published on the subject, to wit, a separate pamphlet
published in England in 1793, and a communication in the Am. Ph. trans,
v. IV. p. 11-20.
In the last mentioned paper, he proceeds also to give an account of
some experiments on the property of water to imbibe different kinds of
air, and the conversion of sp. of wine, into inflammable air.
This paper inserted in the American transactions, was read before that
society in Feb. 1796. In Ap. 1800 another paper was read before the
same society on the production of air by the freezing of water Am. Ph.
trans. v. V. p. 36. In this paper he recapitulates the general result
of his former experiments on the generation of air from water, namely
“that after all air had been extracted from any quantity of water by
heat or by taking off the pressure of the atmosphere, whenever any
portion of it was converted into vapour, a bubble of permanent air
was formed, and this was always phlogisticated. The process with the
Torricellian vacuum (he says) I continued for some years and found the
production of air equable to the last. The necessary inference from
this experiment is, that water is convertible into phlogisticated air,
or that it contains more of this air intimately combined with it than
can be extricated from these processes in any reasonable time.”
Public-domain text, read in full here on John Shaqi.
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