Memoirs of the Distinguished Men of Science of Great Britain Living in the Years 1807-8Walker, William
History
Memoirs of the Distinguished Men of Science of Great Britain Living in the Years 1807-8
Walker, William
Scientists -- Great Britain -- Biography
of which was to re-establish the title of carbon to be ranked among
elementary bodies, which had been denied by Austin, Beddoes, and other
eminent chemists. In this paper he subsequently discovered a fallacy
in his own reasoning, which he exposed before it had been detected
by any other chemist. In 1800 he published in the 'Philosophical
Transactions' his experiments on muriatic acid gas, and in 1803 made
known to the Royal Society his elaborate experiments on the quantity of
gases absorbed by water at different temperature and under different
pressures, the result of which was the establishment of the law that
"water takes up of gas, condensed by one, two or more additional
atmospheres, a quantity which would be equal to twice, thrice, &c. the
volume absorbed under the ordinary pressure of the atmosphere." In
1808 Henry was elected a Fellow of the Royal Society, and in the same
year described in their 'Transactions' a form of apparatus adapted to
the combustion of larger quantities of gases than could be fired in
eudiometric tubes. This apparatus, though now superseded, gave more
accurate results than had ever before been attained. In the following
year (1809) the Copley gold medal was awarded to him for his valuable
contributions to the 'Transactions' of the Royal Society. For the
next fifteen years Dr. Henry continued his experiments on gases,
making known to the Society the results from time to time. In his
last communication, in 1824, he claimed the merit of having conquered
the only difficulty that remained in a series of experiments on the
analysis of the gaseous substances issuing from the destructive
distillation of coal and oil--viz., the ascertaining by chemical
means the exact proportions which the gases, left after the action of
chlorine on oil and coal gas, bear to each other. This he accomplished
by skilfully availing himself of the property (recently discovered
by Döbereiner), in finely divided platinum, of causing gaseous
combinations, and he was thus enabled to prove the exact composition
of the fire-damp of mines. All the experiments of Dr. Henry which have
been previously alluded to bore upon äeriform bodies; but although
these were his favourite studies, his acquaintance with general
chemistry is proved by his 'Elements of Experimental Chemistry,' to
have been both sound and extensive. This work was one of the first
on chemical science published in this country, which combined great
literary elegance with the highest standard of scientific accuracy. His
comparative analysis of many varieties of British and foreign salts
were models of accurate analysis, and were important in dispelling
the prejudices then popular in favour of the latter for economical
purposes. His 'Memoir on the Theories of Galvanic Decomposition'
earned the cordial approval of Berzelius, as being among the first
maintaining that view which he himself so earnestly supported.
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