Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
(_e_) The copper is then brought up to pitch by “poling” in the
manner previously indicated, except that at this final stage, the
testing of the metal and the adjusting of the oxygen proportion are
conducted with much greater precision than was necessary for the simple
production of the sound anode plates. In the present instance, the
character of the metal and its value as a commercial article largely
depend upon the care and accuracy with which the correct “pitch” is
reached and is maintained in the bath during the entire period of
casting of the metal. The poling for the “shaking out” of the gases is
rarely necessary with cathode metal, and the addition of the cover of
carbonaceous material for the purpose of effecting the reduction of the
oxides to the desired extent, is made either at the commencement of
poling or else shortly afterwards. After some time, a series of small
samples is taken at intervals, by means of ladles, and the surface of
the ingot is examined. The depression characteristic of dry copper
gradually becomes less marked, the brick-like fracture appears finer
and finer until it becomes silky, whilst the colour eventually turns to
a very delicate salmon-pink. Meanwhile the mechanical properties have
gradually improved, signs of brittleness disappear, and somewhat larger
samples of the metal, which are now taken and tested, are characterised
by a very marked toughness and strength. This is the moment at which
the poling must cease. The residual copper-oxide has now reached the
proportion which was necessary for the imparting of the best mechanical
properties, and the metal is tough-pitch. The skill of the workman is
now exercised to the highest degree, in maintaining the metal in this
condition during the whole of the subsequent casting period. Oxidation
must be avoided in order to prevent a reversion to dry copper, whilst
any further reducing action removes some of the necessary oxide, and
results in “over-poling.” The metal would then become brittle again,
coarsely fibrous and possibly somewhat spongy in fracture and very pale
in colour, whilst in setting it would show a ridge upon the surface.
In that case it would be necessary to “air” the metal again until it
became dry, and then to pole it back to the “tough-pitch” stage.
The copper, when of correct pitch, is therefore removed from the
furnace and cast at once; this being readily conducted through the
tapping slot, the level of which is gradually lowered. The metal then
flows down the spout to the ladle, and is poured into the moulds
attached to some form of mechanical casting machine; the ingots being
finally dropped into a water-bosh, weighed, sampled, and stacked, and
are then in a condition ready for the market.
Public-domain text, read in full here on John Shaqi.
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