Nitro-Explosives: A Practical TreatiseSanford, P. Gerald (Percy Gerald)
Science
Nitro-Explosives: A Practical Treatise
Sanford, P. Gerald (Percy Gerald)
Celluloid; Explosives
Fulminate of mercury is manufactured upon the large scale by two methods.
One of these, commonly known as the German method, is conducted as
follows:--One part of mercury is dissolved in 12 parts of nitric acid of a
specific gravity of 1.375, and to this solution 16.5 parts of absolute
alcohol are added by degrees, and heat is then slowly applied to the
mixture until the dense fumes first formed have disappeared, and when the
action has become more violent some more alcohol is added, equal in volume
to that which has already been added. This is added very gradually. The
product obtained, which is mercury fulminate, is 112 per cent. of the
mercury employed. Another method is to dissolve 10 parts of mercury in 100
parts of nitric acid of a gravity of 1.4, and when the solution has
reached a temperature of 54 deg. C, to pour it slowly through a glass funnel
into 83 parts of alcohol. When the effervescence ceases, it is filtered
through paper filters, washed, and dried over hot water, at a temperature
not exceeding 100 deg. C. The fulminate is then carefully packed in paper
boxes, or in corked bottles. The product obtained by this process is 130
per cent. of the mercury taken. This process is the safest, and at the
same time the cheapest. Fulminate should be kept, if possible, in a damp
state. Commercial fulminate is often adulterated with chlorate of potash.
~Detonators~, or caps, are metallic capsules, usually of copper, and
resemble very long percussion caps. The explosive is pure fulminate of
mercury, or a mixture of that substance with nitrate or chlorate of
potash, gun-powder, or sulphur. The following is a common cap mixture:--
100 parts of fulminate of mercury and 50 parts of potassium nitrate, or
100 parts of fulminate and 60 parts of meal powder. Silver fulminate is
also sometimes used in caps. There are eight sizes made, which vary in
dimensions and in amount of explosive contained. They are further
distinguished as singles, doubles, trebles, &c., according to their
number. Colonel Cundill, R.A. ("Dict. of Explosives"), gives the following
list:--
No. 1 contains 300 grms. of explosive per 1000.
" 2 " 400 " " " " "
" 3 " 540 " " " " "
" 4 " 650 " " " " "
" 5 " 800 " " " " "
" 6 " 1,000 " " " " "
" 7 " 1,500 " " " " "
" 8 " 2,000 " " " " "
Trebles are generally used for ordinary dynamite, 5, 6, or 7 for
gun-cotton, blasting gelatine, roburite, &c.
Public-domain text, read in full here on John Shaqi.
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