Nitro-Explosives: A Practical TreatiseSanford, P. Gerald (Percy Gerald)
Science
Nitro-Explosives: A Practical Treatise
Sanford, P. Gerald (Percy Gerald)
Celluloid; Explosives
After being cut up into lengths of about 3 inches, the gelatine is rolled
up in cartridge paper. Waterproof paper is generally used. The cartridges
are then packed away in cardboard boxes, which are again packed in deal
boxes lined with indiarubber, and screwed down air tight, brass screws or
zinc or brass nails being used for the purpose. These boxes are sent to
the magazines. Before the boxes are fastened down a cartridge or so should
be removed and tested by the heat test, the liquefaction test, and the
test for liability to exudation. (Appendix, p. 6, Explosives Act, 1875.) A
cartridge also should be stored in the magazine in case of any subsequent
dispute after the bulk of the material has left the factory.
The object of the liquefaction test is to ensure that the gelatine shall
be able to withstand a fairly high temperature (such as it might encounter
in a ship's hold) without melting or running together. The test is carried
out as follows:--A cylinder of the gelatine dynamite is cut from the
cartridge of a length equal to its diameter. The edges must be sharp. This
cylinder is to be placed on end on a flat surface (such as paper), and
secured by a pin through the centre, and exposed for 144 consecutive hours
to a temperature of 85 deg. to 90 deg. F., and during such time the cylinder
should not diminish in height by more than one-fourth of an inch, and the
cut edges should remain sharp. There should also be no stain of
nitroglycerine upon the paper.
The exudation test consists in freezing and thawing the gelatine three
times in succession. Under these conditions there should be no exudation
of nitro-glycerine. All the materials used in the manufacture of gelatine
explosives should be subjected to analytical examination before use, as
success largely depends upon the purity of the raw materials. The
wood-pulp, for instance, must be examined for acidity.
~Properties of the Gelatine Compounds.~--Blasting gelatine is generally
composed of 93 to 95 parts nitro-glycerine, and 5 to 7 parts of nitro-
cellulose, but the relative proportions of explosive base and nitro-
glycerine, &c., in the various forms of the gelatine explosives do not
always correspond to those necessary for total combustion, either because
an incomplete combustion gives rise to a greater volume of gas, or because
the rapidity of decomposition and the law of expansion varies according to
the relative proportions and the conditions of application. The various
additions to blasting gelatine generally have the effect of lowering the
strength by reducing the amount of nitro-glycerine, but this is sometimes
done in order to change a shattering agent into a propulsive force. If
this process be carried too far, we of course lose the advantages due to
the presence of nitro-glycerine. There is therefore a limit to these
additions.[A]
[Footnote A: Mica is said to increase the rapidity of explosion when mixed
with gelatine.]
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