Non-technical chats on iron and steel, and their application to modern industrySpring, La Verne W. (La Verne Ward)
History
Non-technical chats on iron and steel, and their application to modern industry
Spring, La Verne W. (La Verne Ward)
Iron; Steel
It was but twenty years ago that the first outline was drawn and the
whole “fusibility” or “equilibrium diagram” of the iron-carbon alloys
given in the next chapter has practically been developed within this
time. But over this period of twenty or so years the points upon which
these lines Ar_{1}, Ar_{2}, Ar_{3}, Ar_{3·2} and Ar_{3·2·1} are based
have been checked many times and they are now well substantiated. These
lines form but a small part of the complete “iron-carbon diagram.”
The Meaning of the Points
You remember that wrought iron and steels having less than .10% carbon
showed no point Ar_{1}, and that in all other steels this point becomes
stronger as they contain higher and higher carbon. There is little doubt
that the point Ar_{1} exists or results from and because of the carbon
of the alloy. In wrought iron there is no carbon, hence there is no
point Ar_{1}. If the extremely low carbon steels have an Ar_{1} it is so
weak that it cannot be detected.
Had we tested the .45% carbon steel for magnetic properties we would
have found that it lost magnetism at about 1395° F., instead of at 1290°
F., at which temperature the .90% steel became non-magnetic. The point
Ar_{2}, then, shows the temperature at which loss or gain of magnetism
occurs. The electrical conductivity change comes at neither of these
points, Ar_{1}, nor Ar_{2}, but at Ar_{3}.
However, with increase of carbon the line Ar_{3}, which was drawn
through the points, Ar_{3}, rapidly descends. At about .45% or .50%
carbon content, this line Ar_{3}, representing the changes in
conductivity, joins line Ar_{2}. Hence in steels having .45% carbon or
more, there is a common point, or one which in reality is made up of
both points. At this common point the phenomena peculiar to each of the
points occur.
This common line, now called Ar_{3·2}, itself lowers with further
increase of carbon until, in steels of around .90% carbon, there is but
the single point Ar_{3·2·1}, and the phenomena corresponding to all
three of the points occur at this one point at 1290° F., as we found in
our experiments.
As points Ar_{2} and Ar_{3} occur in carbonless iron, they cannot result
in any way from carbon but must have to do with the iron itself. From
their experiences with other materials, chemists and physicists are well
acquainted with such evolutions of heat as occur at Ar_{2} and at
Ar_{3}. These heat absorptions and evolutions, with the sudden
dilatation, gain in conductivity, etc., indicate that some internal
change or reorganization takes place in the iron itself.
Public-domain text, read in full here on John Shaqi.
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