Non-technical chats on iron and steel, and their application to modern industrySpring, La Verne W. (La Verne Ward)
History
Non-technical chats on iron and steel, and their application to modern industry
Spring, La Verne W. (La Verne Ward)
Iron; Steel
Photomicrograph No. 99b is open-hearth iron which is entirely made up of
free ferrite. In No. 3b there is considerable pearlite, here appearing
black, though the sample of steel yet contains but .10% of carbon. In
No. 5, which is of a steel containing .30% of carbon, we have more
pearlite and in No. 22c with .50% carbon we have yet more. Manifestly at
this rate the comparative pearlite areas are growing so that there will
soon be room for no ferrite at all. In No. 23g this has occurred. This,
the photomicrograph of a steel containing .86% of carbon is one of the
steels in which we found that the point of recalescence, loss of
magnetism, decrease in electrical conductivity and rate of expansion
take place all at the one point.
[Illustration:
No. 99b. CARBONLESS IRON
]
[Illustration:
No. 3b. STEEL WITH .1 PER CENT CARBON
]
[Illustration:
No. 5. STEEL WITH .3 PER CENT CARBON
]
[Illustration:
No. 22c. STEEL WITH .5 PER CENT CARBON
]
(_Magnification 60 Diameters._)
Now as we go still farther on up in percentage of carbon content, i.e.
(beyond .86%, we have a white constituent beginning to appear as cell
walls around the grains of the pearlite and this increases with increase
of carbon until, with alloys having carbon around 3%, we have a
proportionately small amount of pearlite while the white areas have so
increased that it appears that the more or less round patches of
pearlite float in a lake of white. This white which appears first as
cell walls, and later in greater and greater quantity is free
cementite.)
[Illustration:
No. 23g. STEEL WITH .9 PER CENT CARBON
]
[Illustration:
No. 24a. STEEL WITH 1.25 PER CENT CARBON
]
[Illustration:
No. 36b. STEEL WITH 2 PER CENT CARBON
]
[Illustration:
No. 109. WHITE CAST IRON WITH 3 PER CENT CARBON
]
(_Magnification 60 Diameters._)
Such are illustrated in photomicrographs Nos. 24a, 36b and 109 which
contain 1.25%, 1.98% and 3.00% of carbon respectively. While steels with
the typical white, free ferrite areas are so soft that a needle-point
will plow furrows across them, those with over 1.25% of carbon have such
excess of free cementite that they are very hard to scratch and too
brittle to use except for special purposes.
[Illustration:
AUSTENITE (WHITE) AND MARTENSITE (DARK) MAGNIFIED 1,000 TIMES THEIR
ACTUAL SIZE
]
So during ordinary cooling from the molten alloy or the slower cooling
of the steel during the annealing process, the martensitic structure
breaks down at the recalescent temperature into pearlite and ferrite
(soft iron) if the carbon content of the steel is lower than about .90%,
or pearlite and the other and very hard constituent, “cementite,” if the
steel has more than .90% of carbon. If the carbon content happens to be
just .90%, or thereabouts, there is exactly sufficient pearlite to make
up the total area of the field shown under the microscope.
Public-domain text, read in full here on John Shaqi.
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