Non-technical chats on iron and steel, and their application to modern industrySpring, La Verne W. (La Verne Ward)
History
Non-technical chats on iron and steel, and their application to modern industry
Spring, La Verne W. (La Verne Ward)
Iron; Steel
While endeavoring to leave out of these articles most of the chemistry
and as much of the technical detail as is consistent with clearness, the
chemistry of combustion and the “gas producer” is so interesting that it
will be well to explain that carbon (coal, coke, wood, etc.) can burn
either in one or two stages. Nearly every one has noticed the blue flame
with which coal burns in the parlor coal heater or in other furnaces
where little draft is used and most of us remember that the gas which is
given off from such a fire has asphyxiated many who were unfortunate
enough to be sleeping in a closed room, when through insufficient
chimney draft or a leaky stove some of the unburnt gas filled the room.
This gas, which is carbon monoxide, is labeled CO in books on chemistry.
It is the result of burning the coal with insufficient air. Chemically
it is explained by the second of the chemical “equations” which follow.
The third equation explains the second stage of the burning which would
occur were further air or oxygen admitted to the upper part of the
furnace.
_The usual one-stage combustion with plenty of air_:
1. C (carbon) + 2O (oxygen) burns to CO_{2} (carbon dioxide).
Non-poisonous.
_The two-stage combustion with insufficient air_:
2. C + O burns to CO (carbon monoxide). Poisonous.
3. CO + O burns to CO_{2}. Non-poisonous.
Carbon monoxide asphyxiates by forming a chemical compound with the
hæmoglobin of the blood, which therefore is prevented from supplying the
body with the oxygen that is required for the sustenance of life.
Carbon dioxide is no such poisonous product, as may be inferred when we
remember that it is the gas with which our carbonated waters are charged
and which is so commonly served with ice cream in ice cream soda.
Public-domain text, read in full here on John Shaqi.
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