Surface tension is that force by which we explain the form of a drop
or of a bubble, of the surfaces external and internal of a “froth” or
collocation of bubbles, and of many other things of like nature and in
like circumstances[272]. It is a property of liquids (in the sense at
least with which our subject is concerned), and it is manifested at or
very near the surface, where the liquid comes into contact with another
liquid, a solid or a gas. We note here that the term _surface_ is to
be interpreted in a wide sense; for wherever we have solid particles
imbedded in a fluid, wherever we have a non-homogeneous fluid or
semi-fluid such as a particle {206} of protoplasm, wherever we have
the presence of “impurities,” as in a mass of molten metal, there we
have always to bear in mind the existence of “surfaces” and of surface
tensions, not only on the exterior of the mass but also throughout its
interstices, wherever like meets unlike.
Surface tension is due to molecular force, to force that is to
say arising from the action of one molecule upon another, and it
is accordingly exerted throughout a small thickness of material,
comparable to the range of the molecular forces. We imagine that within
the interior of the liquid mass such molecular interactions negative
one another: but that at and near the free surface, within a layer or
film approximately equal to the range of the molecular force, there
must be a lack of such equilibrium and consequently a manifestation of
force.
The action of the molecular forces has been variously explained. But
one simple explanation (or mode of statement) is that the molecules
of the surface layer (whose thickness is definite and constant) are
being constantly attracted into the interior by those which are more
deeply situated, and that consequently, as molecules keep quitting the
surface for the interior, the bulk of the latter increases while the
surface diminishes; and the process continues till the surface itself
has become a minimum, the _surface-shrinkage_ exhibiting itself as a
_surface-tension_. This is a sufficient description of the phenomenon
in cases where a portion of liquid is subject to no other than _its
own molecular forces_, and (since the sphere has, of all solids, the
smallest surface for a given volume) it accounts for the spherical form
of the raindrop, of the grain of shot, or of the living cell in many
simple organisms. It accounts also, as we shall presently see, for a
great number of much more complicated forms, manifested under less
simple conditions.
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