Chemical apparatus; Electroplating; Glass blowing and working; Glass coatings; Glass grinding and polishing; Lampwork; Mirrors
Sooner or later, however, a sufficient length of bubble-free quartz
can be obtained. It must not be supposed that it is always necessary
to eliminate bubbles as perfectly as is contemplated in the foregoing
description of the treatment, but for special purposes it may be
essential to do so, and in any case the reader's attention is directed
to a possible source of error.
It may be mentioned in connection with this matter that crystals of
quartz may look perfectly white and clear, and yet contain impurity.
For instance, traces of sodium are generally present, and lithium was
found in large spectroscopic quantity in five out of six samples of
the purest crystals in my laboratory. The presence of lithium in rock
crystal has also been detected by Tegetmeier (Vied. Ann, xli. p.
19, 1890).
After some practice in preparing rods and freeing them of bubbles the
operator will notice a distinct difference in the fusibility of the
samples of quartz he investigates, though all may appear equally pure
to the unaided eye. It should be mentioned, however, that high
infusibility cannot always be taken as a test of purity, for the most
infusible, or rather most viscous, sample examined by the writer
contained more lithium than some less viscous samples.
Fig. 65.
During the process of freeing the quartz from bubbles the lithium and
sodium will be found to burn away, or at all events to disappear.
A rod of quartz, say three inches long, one-sixteenth of an inch in
diameter, and free from bubbles for half an inch of its length, even
when examined by a strong lens, is suitable for drawing into threads.
The rod is manipulated exactly in the manner described under
glass-blowing, and is finally drawn down at the bubble free part into
a needle, say 0.02 inch in diameter (No. 25 on the Birmingham wire
gauge), and 2 inches long.
Fig. 66.
There is one peculiarity about fused quartz which renders its
manipulation easier than that of glass--it is impossible to break
fused quartz, however suddenly it be thrust into the blow-pipe flame.
A rod having a diameter of three-sixteenths of an inch--and perhaps
much more--may be brought right up to the tip of the inner cone of
the oxy-gas flame and held there-till one side fuses, the other being
comparatively cool, without the slightest fear of precipitating a
smash. In seven years' experience I have never seen a bit of once
fused quartz broken by sudden heating; whether it might be done if
sufficient precautions were taken I do not know.
The reason of the fortunate peculiarity of quartz in this respect is,
I presume, to be found in the fact that quartz once it has been fused
is really a very strong material indeed, and is also probably the
least expansible substance known. From some experiments of the writer
upon the subject, it may be concluded that at the most quartz which
has been fused expands only about one-fifth as fast as flint-glass, at
all events between 20 deg. and 70 deg. C.
Public-domain text, read in full here on John Shaqi.
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